The treatment by advanced oxidation processes (AOPs) of waters contaminated by organic pollutants and containing also innocuous bromide ions may generate bromate ions as a co-product. In the present work heterogeneous photocatalysis and ozonation have individually been applied and in combination (integrated process) to degrade the organic compounds in water containing also bromide anions. The r...

Three simple, economical, precise, reliable and reproducible visible spectrophotometric methods (A, B and C) have been developed for the estimation of Levetiracetam in bulk as well as in Tablet formulation. The developed methods A, B and C are based on the formation of chloroform extractable complex of Levetiracetam with Bromocresol green (method A), Bromophenol blue (method B) and Bromothymol ...

A new plate method was developed for rapid screening of Ketogulonicigenium vulgare mutants overproducing 2-keto-l-gulonic acid (2-KLG). The screening methodology took the advantage of the acidity caused by 2-KLG, which changes the color of bromothymol blue (pH indicator) from blue to yellow. Using the proposed method, a mutant, K. vulgare 65, was selected from 20,000 colonies produced by a stra...

Semiconductor heterogeneous photocatalysis, the subject of this review, is a versatile, low-cost and environmentally benign treatment technology for a host of pollutants. These may be of biological, organic and inorganic in origin within water and air. The efficient and successful application of photocatalysis demands that the pollutant, the catalyst and source of illumination are in close prox...

The use of chlorine bleaching in study and pulp industry has resulted in chlorinated phenol contaminated wastewater from that industry. A new wastewater treatment process, sonophotodegradation of 2,4,6-trichlorophenol (TCP) in a heterogeneous aqueous system was investigated and reported in this study. TCP was degraded with ultrasonic or ultraviolet irradiation or a combination of both, in the p...

The synergistic effect of ultrasound, the heterogeneous Fenton reaction and photocatalysis was studied using a nickel foam (NF)-supporting TiO₂ system and rhodamine B (RhB) as a target. The NF-supporting TiO₂ system was prepared by depositing TiO₂ on the skeleton of NF repeatedly and then calcining it. To optimize the conditions and parameters, the catalytic activity was tested in four systems ...

Nutrients and environmental chemicals, including endocrine disruptors, have been incriminated in the current increase in male reproductive dysfunction, but the underlying mechanisms remain unknown. The gastrointestinal tract represents the largest surface area exposed to our environment and thereby plays a key role in connection with exposure of internal organs to exogenous factors. In this con...

H photocatalysis is of broad interest in materials chemistry and materials science, particularly with the rapid growth of research attention being directed toward energy-related applications, pollution mitigation, and other related areas of environmental impact. A literature survey reveals more than 9000 papers with the word photocatalyst or photocatalysis in the title published during the last...

The application of heterogeneous photocatalysis in industrial scale has been hindered by a lack of simple mathematical models that can be easily applied to reactor design and scale-up. This work intends to use a simple mathematical model for predicting methylene blue (MB) degradation in a slurry-annular photocatalytic reactor using zinc oxide (ZnO) hybridized with reduced graphene oxide (rGO)-Z...

Photocatalytic oxidation of the sulfur-containing compounds, trimethylene sulfide (C3H6S), propylene sulfide (C3H6S), thiophene (C4H4S), and methyl disulfide (C2H6S2), was carried out using an annular plug flow reactor with TiO2 in a supported form. Formation of products and byproducts was monitored in real time using a mass spectrometry online system. Mineralization of the sulfur-containing co...