this  article  provides  an  overview  on  preparation,  design,  crystal structure  and  properties  of  some  metal-organic  frameworks  of carboxylate coordination polymers mixed with pyridine-functionality linkers  prepared  in  our  laboratory.  the  article  covers  coordination polymers  in  two-  and  three-dimensional  supramolecular architectures. the reported coordination polymers ex...

This  article  provides  an  overview  on  preparation,  design,  crystal structure  and  properties  of  some  metal-organic  frameworks  of carboxylate coordination polymers mixed with pyridine-functionality linkers  prepared  in  our  laboratory.  The  article  covers  coordination polymers  in  two-  and  three-dimensional  supramolecular architectures. The reported coordination polyme...

CuO nano particles were obtained by calcination of nano-sized  [Cu(C4H4O4)(bipy)(H2O)2].2H2O (1) and [Cu(2‚2′-bipy)](C4H4O4)0.5(NO3)(H2O) (2) which are two  Cu(II) coordination polymers. The two coordination polymers [Cu(C4H4O4)(bipy)(H2O)2].2H2O and [Cu(2‚2′-bipy)](C4H4O4)0.5(NO3)(H2O) were synthesized and characterized by Fourier transform infrared spectra (FT-IR spectroscopy), thermal gravim...

One-dimensional (1D) halide-bridged Cu(I)–Ni(II) heterometal coordination polymers containing a hexamethylene dithiocarbamate (Hm-dtc) ligand have been synthesized and crystallographically characterized. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) levels of the coordination polymers were estimated using UV-Vis-NIR and photoelectron spectroscopies...

This award account focuses on metallo-supramolecular polymers (MSPs), which are composed of metal ions and multitopic ligands, as a new branch coordination polymers. Their high solubility in polar solvents, such methanol or water their amorphous nature the solid state, enabled formation thin layers MSPs with uniform thickness an electrode surface by spin- spray-coating polymer solution, resulti...

Two new nano-sized lead(II) and mercury(II) coordination polymers, [Pb(2-bpdh)(NO3)2(H2O)]n(1); (2-bpdh = 2,5-bis(2-pyridyl)-3,4-diaza- 2,4-hexadiene)} and [Hg(4-bpdb)(SCN)2]n (2); (4-bpdb= 1,4-bis(4- pyridyl)-3,4-diaza-1,3-butadiene) were synthesized by a sonochemical method. The structure of 1 may be considered coordination polymer of lead(II) and Single crystal X–ray analysis of compound ...

two new nano-sized lead(ii) and mercury(ii) coordination polymers, [pb(2-bpdh)(no3)2(h2o)]n(1); (2-bpdh = 2,5-bis(2-pyridyl)-3,4-diaza-2,4-hexadiene)} and [hg(4-bpdb)(scn)2]n (2); (4-bpdb= 1,4-bis(4-pyridyl)-3,4-diaza-1,3-butadiene) were synthesized by a sonochemical method. the structure of 1 may be considered coordination polymer of lead(ii) and single crystal x–ray analysis of compound 2reve...

Coordination polymers have attracted an enormous interest among chemists due to their novel physical and chemical properties. This review describes the role of 4,4'-bipyridine in discovering various coordination polymers with novel topologies that range from one-dimensional to three dimensional. The geometries of coordination polymers of bipy include linear, zigzag, four-fold helices, molecular...

Two new linear silver(I) nitrate coordination polymers with bitopic ligand 1,1,2,2tetra(pyrazol-1-yl)ethane were synthesized. Synthesized compounds were characterized by IR spectroscopy, elemental analysis, powder X-ray diffraction and thermal analysis. Silver coordination polymers demonstrated a yellow emission near 500 nm upon excitation at 360 nm. Crystal structures of coordination polymers ...