Ali Morsali
Department of Chemistry, Faculty of Basic Sciences, Tarbiat Modares University, Iran
[ 1 ] - Use of nanoscale zero-valent iron to improve the shear strength parameters of gas oil contaminated clay
In recent years, the nanoscale zero-valent iron (NZVI) particles have been used successfully for the degradation of hydrocarboncompounds and remediation of other pollutants. Nevertheless, as far as we know, there is no specific study on the improvement of thegeotechnical properties of contaminated soils with hydrocarbon compounds by NZVI. This study used NZVI particles to remove gasoil in a cla...
[ 2 ] - Sonochemical Synthesis of a Cobalt(II) Coordination Polymer Nano-structure with azo ligand: A New Precursor for Preparation Pure Phase of Co3O4 Nanostructure
A new nano-sized cobalt(II) coordination polymer, (CoL1).0.5DMF.1.5CH3OH(1); [H2L1 = 5-(4-Carboxy phenyl azo) salicyilic acid] has been synthesized by a sonochemical method. The thermal stability of compound 1 was studied by thermo- gravimetric and differential thermal analyses. Nano-structure of this coordination polymer was characterized by elementa...
[ 3 ] - Sonochemical Synthesis of two New Nano-structured Lead(II) and Mercury(II) Coordination Polymers
Two new nano-sized lead(II) and mercury(II) coordination polymers, [Pb(2-bpdh)(NO3)2(H2O)]n(1); (2-bpdh = 2,5-bis(2-pyridyl)-3,4-diaza- 2,4-hexadiene)} and [Hg(4-bpdb)(SCN)2]n (2); (4-bpdb= 1,4-bis(4- pyridyl)-3,4-diaza-1,3-butadiene) were synthesized by a sonochemical method. The structure of 1 may be considered coordination polymer of lead(II) and Single crystal X–ray analysis of compound ...
[ 4 ] - Sonochemical Synthesis of a New Nano Lead(II) Coordination Polymer with 2,5-bis(2-pyridyl)-3,4-diaza-2,4- hexadiene ligand: A Precursor to Produce Pure Phase Nano- sized Lead(II) Oxide
A new nano-sized lead(II) coordination polymer, [Pb(2-bpdh)(NO3)2]n (1); (2-bpdh = 2,5-bis(2-pyridyl)-3,4-diaza-2,4-hexadiene)}, was synthesized by a sonochemical method. The structure of 1 may be considered coordination polymer of lead(II) consist of metallocyclicchains formed by bridging NO3- and 2-bpdh l...
[ 5 ] - ارزیابی و تحلیل توان گرادیان شوری در مصب رودخانۀ اروند بر پایۀ روش الکترودیالیز معکوس
Electrical power of salinity gradient is one of the sources for renewable energy. This energy can be obtained by mixing two kinds of water with different concentrations. In a river estuary, fresh water naturally mixes with sea water without any obstruction. Reveres electro dialysis (RED) is one of the suitable and practical methods for controlling this unobstructed mixture and extracting energy...
[ 6 ] - Application of a nanoporous metal organic framework based on iron carboxylate as drug delivery system
In the present study, a nanoporous metal organic framework (MOF) based on iron metal and amino terephthalate ligand MIL-101-NH2-Fe has been used as a carrier for loading and in vitro release of 5-flurouracil (5-FU) anticancer drug. The 5-FU drug loaded MOF was 13 wt % by using thermogravimetric analysis (TGA). The 5-FU release was monitored under physiological condition at 37°C, pH 7.4 in simul...
[ 7 ] - Application of a nanoporous metal organic framework based on iron carboxylate as drug delivery system
In the present study, a nanoporous metal organic framework (MOF) based on iron metal and amino terephthalate ligand MIL-101-NH2-Fe has been used as a carrier for loading and in vitro release of 5-flurouracil (5-FU) anticancer drug. The 5-FU drug loaded MOF was 13 wt % by using thermogravimetric analysis (TGA). The 5-FU release was monitored under physiological condition at 37°C, pH 7.4 in simul...
[ 8 ] - Synthesis and Crystal Structure of [Pb(gly)2]n; New lead(II) Coordination Polymer with Glycine Ligand
[Pb(gly)2]n (1) (gly is the abbreviation of Glycine) have been synthesized and characterized by elemental analyses, IR, 1H NMR and 13C NMR spectroscopy. The single crystal structure of 1 show the complex is 2D coordination polymer with octahedral environment that is formed into 3D supramolecule through hydrogen bond. Structural determination of compound 1 reveals the Pb(II) ion is four coordina...