ABSTRACT When Ti(OiPr)4 was reacted with increasing proportions of methacrylic acid (McOH), the compounds Ti2(OiPr)6(OMc)2(iPrOH), Ti6O4(OiPr)8(OMc)8, Ti9O8(OiPr)4(OMc)16, and Ti8O8(OMc)16 were obtained in sequence. This allowed conclusions on the relative ratio of substitution and hydrolysis reactions, the latter being due to ester formation between the acid and cleaved alcohol. This ratio is ...

The plasma polymerization of NIPAAM and titanium isopropoxide monomers into responsive ultrathin films with responsive optical properties using plasma enhanced chemical vapor deposition is reported. The composite ultrathin films possess a large window for potential changes in their refractive index from 1.60 to 1.95. We demonstrated that these polymer films exhibit fast (transition time below 2...

Mesoporous TiO2 microspheres assembled from TiO2 nanoparticles with specific surface areas as high as 150 m(2) g(-1) were synthesized via a facile one-step solvothermal reaction of titanium isopropoxide and anhydrous acetone. Aldol condensation of acetone gradually releases structural H2O, which hydrolyzes and condenses titanium isopropoxide, forming TiO2 nanocrystals. Simultaneous growth and a...

Titania pillared montmorillonite from Indonesian montmorillonite by using titanium isopropoxide as precursor was successfully prepared. Physico-chemical character of material by using x-ray diffraction, gas sorption analyzer, diffuse reflectance UV-Visible, scanning electron microscope (SEM) and energy dispersive x-ray (EDAX) showed the dipersion of titania in dominantly anatase phase that is t...

A series of titanium trichloride complexes , ligated with claw-type tetradentate aminophenolate ligands were synthesized from the direct reaction of TiCl4(THF)2 with 1 equiv. of the corresponding aminophenol in the presence of triethylamine. For comparison purposes, titanium isopropoxide complexes were also synthesized via the reaction of Ti(O(i)Pr)4 and 1 equiv. of the proligand. Similar react...

With 780-nm, 250-fs laser pulses, ultrafast optical nonlinearity has been observed in a series of thin films containing poly~methyl methacrylate! (PMMA)-TiO2 nanocomposites, which are synthesized by a simple technique of in-situ sol-gel/polymerization. The best figures of merit are found in one of the films prepared with a 60 wt % of titanium isopropoxide. Transmission electron microscopy shows...

The present study reports on the introduction of various nanocatalysts containing nickel (Ni) nanoparticles (NPs) embedded within TiO2 nanofibers and TiO2 microparticles. Typically, a sol-gel consisting of titanium isopropoxide and Ni NPs was prepared to produce TiO2 nanofibers by the electrospinning process. Similarly, TiO2 microparticles containing Ni were prepared using a sol-gel syntheses p...