an efficient green route for the preparation of naphthoxazinones, applying a three-component one-pot condensation reaction of 2-naphthol, aromatic aldehyde and urea in the presence of nano silica supported ferric chloride under solvent-free conditions has been developed. the present procedure offers several advantages such as short reaction time, simple workup, recovery and reusability of the c...

the knoevenagel condensation of aromatic aldehydes with barbituric acid, dimedone and malononitrile occurred in the presence of bf3/nano-γ-al2o3 at room temperature in ethanol. this catalyst is characterized by powder x-ray diffraction (xrd), fourier transform infrared spectroscopy (ft-ir), thermal gravimetric analysis (tga), field emission scanning electron microscopy (fesem) and energy-disper...

two simple protocols for the synthesis of three-component condensation reaction of an aldehyde, β-ketoester and urea or thiourea to obtain the 3, 4-dihydropyrimidin-2(1h)-ones (thiones) using nano silica phosphoric acid are reported. short reaction times, high yields, reusability of catalyst and easy workup are some advantages of these protocols.

two  simple  protocols  for  the  synthesis  of  1,  2,  4,  5-  tetrasubstitutedimidazoles  using  nano-spa  as  a  reusable,  eco-  friendly,  inexpensive,  and  efficient  catalyst  are  reported.  short   reaction  times,  high  yields,  scale-up  and  easy  workup  are  the   advantages of these protocols.

A magnetic nanoparticle catalyst was readily prepared from inexpensive starting materials which catalyzed the Hantzsch reaction. High catalytic activity and ease of recovery from the reaction mixture using an external magnet, and several reuse times without significant losses in performance are additional eco-friendly attributes of this catalytic system.

Background : Effluents containing synthetic dyes are hazardous to ecological systems and public health. Methylene blue is an important chemical aromatic dye which commonly used in textile industries. Due to being aromatic, it is often toxic, carcinogenic and mutagenic. The goal of this study was to investigate the efficiency of ZnO nano particles photocatalytic process for decolorization of met...

A carbon nanotube-gold nanohybrid was used as catalyst for the reduction of molecular oxygen in acidic and alkaline media, the relevant cathode reaction in fuel cells. In alkaline medium, the nanohybrid exhibits excellent activity with a dominant 4e(-) reduction of O2 and low overpotential requirement compared to previously reported nano-gold materials. This property is linked to its capability...

Nano-particles of polycrystalline Zn Fe2 O4 are prepared using sol-gel method with Ni, and Sm. They are obtained as dried gel after the successful chemical reaction of their respective metal nitrate solutions in the midst of citric acid as catalyst. Synthesis of materials is confirmed using XRD from the report of single phase polycrystalline ferrite material. The magnetic properties of Zn-ferri...

The challenge of estimating the crystalline-fraction of dense randomly-oriented nano-particles, contained in a (less-dense) amorphous support, is increasingly important in fields as diverse as heterogeneous-catalyst design and electronic-data storage. Lattice-fringe visibility-analysis [1,2] is a potential tool in this context, but of course interfering contrast from the amorphous support (as w...