a capillary electrophoresis method was used for assay of some degradation products of carvedilol. the optimized parameters were as; running buffer 80 mm acetate dissolved in methanol/ethanol mixture (65:35 v/v), applied voltage of 19 kv, temperature is 20 ºc and the wavelength range of 200-350 nm. the results indicate that the proposed ce method could effectively separate carvedilol from its de...

a simple and reliable method for quick estimation of the dielectric constant of a binary solvent mixture is proposed. the validity of the proposed method has been tested for a broad range of binary solvent mixtures

A simple and reliable method for quick estimation of the dielectric constant of a binary solvent mixture is proposed. The validity of the proposed method has been tested for a broad range of binary solvent mixtures

Numerical methods to predict the solubility of anthracene in mixed solvents have been proposed. A minimum number of 3 solubility data points in sub-binary solvents has been employed to calculate the solvent-solute interaction terms of a well established colsolvency model, i.e. the combined nearly ideal binary solvent/Redlich-Kister model. The calculated interaction terms were used to predict th...

the solubility of naproxen in binary mixtures of polyethylene glycol 200 (peg 200) + water at the temperature range from 298.0 k to 318.0 k were reported. the combinations of jouyban-acree model + van’t hoff and jouyban-acree model + partial solubility parameters were used to predict the solubility of naproxen in peg 200 + water mixtures at different temperatures. combination of jouyban-acree m...

the complexation reactions between mg2+, ca2+, sr2+ and ba2+ metal cations with 15-crown-5 (15c5) were studied in acetonitrile (an)-methanol (meoh) binary mixtures at different temperatures using conductometric method. 15c54 forms 1:1 complexes with mg2+, ca2+ and sr2+ cations in solutions. the ma2+ cation forms a 2:1 complex (ratio of lighand to cation) in solutions. a linear relation was obse...

Instead of the chlorofluorocarbon specified as the ozone-depleting substance, a chlorinated organic compound, hydrocarbon, alcohol, etc. are used as an alternative washing solvent, and they are used as a mixed solvent in many cases. Therefore, adsorption operation of binary systems is needed. Furthermore, since azeotropic may happen, in the case of the design of a solvent recovery system and op...

a spectrophotometric method is used to determine the acidity constants of some derivatives of 9,10-anthraquinone in binary methanol-water mixtures at 25 °c. there is a linear inverse relationship between pka of all acids and the mole fraction of methanol in the mixed solvent. the influence of substituents in the molecular structure on the ionization constants is discussed.

       The Extended Hildebrand Solubility Parameter Approach (EHSA) is used to estimate the solubility of satranidazole in binary solvent systems. The solubility of satranidazole in various water-PEG 400 mixtures was analyzed in terms of solute-solvent interactions using a modified version of Hildebrand-Scatchard treatment for regular solutions. The solubility equation employs term interaction ...

the extended hildebrand solubility parameter approach (ehsa) is used to estimate the solubility of satranidazole in binary solvent systems. the solubility of satranidazole in various water-peg 400 mixtures was analyzed in terms of solute-solvent interactions using a modified version of hildebrand-scatchard treatment for regular solutions. the solubility equation employs term interaction energy ...