نتایج جستجو برای: bronsted acid
تعداد نتایج: 747476 فیلتر نتایج به سال:
Cracking of an all-trans n-alkane, via idealized Lewis acid and Bronsted acid catalysis, was examined using density functional theory. Optimized geometries and transitions states were determined for catalyst-reactant complexes, using AlCl3 and HCl.AlCl3 as the Lewis and Bronsted acids. For the Lewis acid cycle, hydride-transfer steps are seen to have large barriers in both forward and reverse d...
sulfonic acid-based precursors (sap) play an important role in tailoring mesoporous silica’s and convert them to a solid acid catalyst with a bronsted-type nature. these kinds of solid acids contribute to sustainable and green chemistry by their heterogeneous, recyclable, and high efficiency features. therefore, knowing the properties and reactivity of saps can guide us to manufacture a sulfona...
The performance of zeolite catalysts depends not only on the strength and number Bronsted acid (or exchange) sites but also synergistic effects derived from their proximity, in particular, an...
A water soluble, Bronsted acid, 5-sulfosalicylic acid as an efficient organocatalyst was used for the synthesis of physiologically active 2-substituted benzimidazole derivatives from o-phenylenediamine and aromatic aldehydes in ethanol at reflux condition. Cost-effectiveness, use of non-hazardous solvents, metal free and commercially available catalyst, single-step, environmentally fri...
A water soluble, Bronsted acid, 5-sulfosalicylic acid as an efficient organocatalyst was used for the synthesis of physiologically active 2-substituted benzimidazole derivatives from o-phenylenediamine and aromatic aldehydes in ethanol at reflux condition. Cost-effectiveness, use of non-hazardous solvents, metal free and commercially available catalyst, single-step, environmentally fri...
According to the Bronsted definition, any compound which has a hydrogen atom is an acid, since itmay be lost as a proton. A thermodynamical cycle is proposed to calculate absolute pKa values forBronsted acids in aqueous solution. The equilibrium of dissociation of a Bronsted acid depends onthe interaction of the acid and its conjugate base with solvent molecules. There fore the pKa valuedepends...
A one-step synthesis of 4-arylquinoline-2-carboxylates along with their antiprotozoal activity against the pathogenic parasite Toxoplasma gondii is reported. Mechanistic insights into the role of Lewis acid (silver triflate) versus Bronsted acid (triflic acid) catalysis are revealed clarifying aspects of the mechanism of the quinoline synthesis.
a water soluble, bronsted acid, 5-sulfosalicylic acid as an efficient organocatalyst was used for the synthesis of physiologically active 2-substituted benzimidazole derivatives from o-phenylenediamine and aromatic aldehydes in ethanol at reflux condition. cost-effectiveness, use of non-hazardous solvents, metal free and commercially available catalyst, single-step, environmentally friendly gre...
Acid-base Reactions Induced by a Plasma Phase on Liquid Targets : Bronsted Acidity and Oxo Synthesis
The interactions between liquid targets and plasmas provided by a d.c. point-to-plane corona device operated under p = 1 atm. are considered in terms of both Bronsted and Lewis acid-base reactions. The treatments of aqueous solutions by the chargeless species of air or NH3 plasmas increase the Bronsted acidity of the target, and for an air plasma, the pH decrease is a linear function of the qua...
according to the bronsted definition, any compound which has a hydrogen atom is an acid, since itmay be lost as a proton. a thermodynamical cycle is proposed to calculate absolute pka values forbronsted acids in aqueous solution. the equilibrium of dissociation of a bronsted acid depends onthe interaction of the acid and its conjugate base with solvent molecules. there fore the pka valuedepends...
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