Using density functional theory, we investigate the equilibrium structure, stability, and electronic properties of nanostructured, hydrogen-terminated diamond fragments. The equilibrium atomic arrangement and electronic structure of these nanostructures turn out to be very similar to bulk diamond. We find that such diamondoids may enter spontaneously into carbon nanotubes. Polymerization inside...

To celebrate the tenth anniversary of Nano Letters, this short commentary discusses a scientific issue of current interest, increased electron-electron interactions in nanostructures. The two major factors of reduced dimensionality and low screening are analyzed. Carbon nanotubes and graphene are molecular in many of their properties and show strong electron-electron interactions. In specific c...

We present a comparative study where carbon nanostructures were prepared by electron and ion beam methods. The deposited thin films were analysed by Raman analysis, nanoindentation, Energy dispersive X-ray analysis (EDX) and atomic force microscopy (AFM). In most conditions, the material formed is hydrogenated amorphous carbon. This study was used to form sharp AFM supertip structures which wer...

Focused electron beam induced deposition (FEBID) is a versatile tool for the direct-write fabrication of nanostructures on surfaces. However, FEBID nanostructures are usually highly contaminated by carbon originating from the precursor used in the process. Recently, it was shown that platinum nanostructures produced by FEBID can be efficiently purified by electron irradiation in the presence of...

A phosphorus allotrope that has not been observed so far, ring-shaped phosphorus consisting of alternate P8 and P2 structural units, has been assembled inside multi-walled carbon nanotube nanoreactors with inner diameters of 5-8 nm by a chemical vapor transport and reaction of red phosphorus at 500 °C. The ring-shaped nanostructures with surrounding graphene walls are stable under ambient condi...

Carbon nanotubes have an important role in reinforcing nanocomposits. Many experimental observations have shown that in the most nanostructures such as nanocomposites, carbon nanotubes (CNTs) are often characterized by a certain degree of waviness along their axial direction. In the present paper, the effects of initial curvature, influence of surrounding medium that is modeled as Winkler elast...

Invited and Contributed Oral Presentations A01. The formation and observation of individual vacancies in carbon nanotubes by a focused electron beam Florian Banhart University of Strasbourg, France Coauthor(s) : J. A. Rodriguez-Manzo Modern scanning transmission electron microscopes (STEM) with aberration correctors enable us to focus an extremely intense electron beam onto an Angstrom-size spo...

We report the systematic studies on the fabrication of aligned, uniform, and highly dense diamond nanostructures from diamond films of various granular structures. Self-assembled Au nanodots are used as a mask in the self-biased reactive-ion etching (RIE) process, using an O2/CF4 process plasma. The morphology of diamond nanostructures is a close function of the initial phase composition of dia...

This study focuses on elucidating the bond breaking steps involved in the electron beam induced deposition (EBID) of nanostructures created from the organometallic precursor cobalt tricarbonyl nitrosyl (Co(CO)3NO) by studying the effect of 500 eV incident electrons on nanometer scale films of Co(CO)3NO. Experiments were performed under ultrahigh vacuum conditions, using a suite of surface analy...