نتایج جستجو برای: chiral stability
تعداد نتایج: 336584 فیلتر نتایج به سال:
ab initio calculations at hf/6-31g* level of theory for geometry optimization and mp2/6-31g*//hf/6-31g* for a single point total energy calculation are reported for the importantenergy-minimum conformations and transition-state geometries of 1, 3-diazacyclohepta-1, 2-diene (2) and 1, 3-diazacycloocta-1, 2-diene (3). the c2 symmetric twist-chair (2-tc)conformation of 2 is calculated to be 7.4 kj...
an efficient one-pot three-component procedure for the synthesis of new chiral spiro-oxindolopyrrolizidines with highly regio-, diastereo-, and enantioselective from 1,3-dipolar cycloaddition of azomethine ylides and optically pure active cinamoyl oxazolidinone are described. the process occurs at room temperature in aqueous ethanol as green solvent and in the absence of any bidentate chelating...
in recent years there has been considerable interest in the synthesis and separation of enantiomers of organic compounds especially because of their importance in the biochemistry and pharmaceutical industry. high-performance liquid chromatography is a very useful method for the direct separation of enantiomers. however, about 30−40 years ago, commercially available chiral stationary phases wer...
In recent years there has been considerable interest in the synthesis and separation of enantiomers of organic compounds especially because of their importance in the biochemistry and pharmaceutical industry. High-performance liquid Chromatography is a very useful method for the direct separation of enantiomers. However, about 30−40 years ago, commercially available chiral stationary phases wer...
one of the problems encountered in ce separations of basic compounds is the adsorption of analytes onto the negatively charged capillary wall which could lead to poor repeatability of migration time and peak area. additionally, separation of enantiomers of chiral of basic drugs is commonly carried out in low ph buffer which contributes to strong ionic interaction of the cationic drug ions with ...
We introduce an index indicating the occurrence of chiral fermions at the intersection of branes in matrix models. This allows to discuss the stability of chiral fermions under perturbations of the branes.
We report the most sensitive direct search for pair production of fourth-generation bottomlike chiral quarks (b') each decaying promptly to tW. We search for an excess of events with an electron or muon, at least five jets (one identified as due to a b or c quark), and an imbalance of transverse momentum by using data from pp collisions collected by the CDF II detector at Fermilab with an integ...
It has been known for some time that the Boltzmann weights of the chiral Potts model can be parametrized in terms of hyperelliptic functions, but as yet no such parametrization has been applied to the partition and correlation functions. Here we show that for N = 3 the function S(t p) that occurs in the recent calculation of the order parameters can be expressed quite simply in terms of such a ...
in this study, kinetics and mechanism of the sulfur dioxide adsorption on the single-walled carbon nanotubes (cnt) are investigated. three single-walled carbon nanotubes, including the armchair (6,6), chiral (6,5) and zigzag (6,0) cnts were chosen as the models and the different orientations of so2 molecule relative to the cnt axis were considered. the b3lyp functional within the 6-31g(d) basis...
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