In the absence of solvent, highly selective hydrogenation of o-chloronitrobenzene and m-chloronitrobenzene, with selectivity to the corresponding chloroanilines of ≥99.4% and complete conversion of the substrates, was realized over a robust Pt/Fe(3)O(4) catalyst which was prepared by adsorbing Pt nanoclusters on a Fe(3)O(4) support.

background & aims of the study: p-chloronitrobenzene is a benzoic compound that widely used in many chemical industrials. p-chloronitrobenzene may be absorbed through the skin and is suspected to causing cancer. so, developing an easy method to remove of it from the environment is necessary. equilibrium isotherms and adsorption kinetics of p-chloronitrobenzene onto modified silk waste were stud...

Background & Aims of the Study: p-Chloronitrobenzene is a benzoic compound that widely used in many chemical industrials. p-Chloronitrobenzene may be absorbed through the skin and is suspected to causing cancer. So, developing an easy method to remove of it from the environment is necessary. Equilibrium isotherms and adsorption kinetics of p-Chloronitrobenzene onto modified sil...

The direct redox reaction (galvanic displacement) between Pd(2+) and substrate Si was used to deposit Pd on Si, and the Pd-Si catalysts enabled a chemoselective hydrogenation of para-chloronitrobenzene with the selectivity for para-chloroaniline higher than 99.9% at complete conversion of para-chloronitrobenzene.

NQR studies o f a number of molecular complexes with p-chloronitrobenzene and o-chloronitrobenzene as acceptors and different hydrocarbons as donors were carried out. A linear relationship between the NQR shift and the ionization potentials o f the donors is obtained. Maksyutin’s idea o f a positive shift with respect to acceptors having a quadrupolar nucleus is shown to hold in those systems. ...

High quality noncrystalline NiPB nanotubes were synthesized and exhibited high efficiency for the catalytic hydrogenation of p-chloronitrobenzene due to the characteristic confinement effect of the nanotubes.

The title compound, C10H9Cl2N3O3S, adopts a trans-cis conformation with respect to the position of chloropropionyl and chloronitrobenzene groups respectively, against the thiono about their C-N bonds. The conformation is stabilized by an intra-molecular N-H⋯O hydrogen bond. In the crystal, there is a short Cl⋯Cl contact with a distance of 3.386 (13) Å.