The thermomechanical degradation of blends made from polypropylene and polystyrene, with or without compatibilizer, was studied using an internal mixer coupled to a torque rheometer. The blends processed without compatibilizer presented regular and expected results regarding torque reduction, with evidence of chain scission. The blends processed with the block copolymer of styrene and butadiene...

Polylactic acid-g-polyvinyl acetate (PLLA-g-PVAc) was used as a compatibilizer for 50/50 starch/PLLA blend. PLLA-gPVAc with different mol% of PVAc contents were prepared by grafting PVAc onto PLLA backbone via free radical polymerization in solution process. Various conditions such as type and the amount of initiator, monomer concentration, polymerization time and temperature were studied. Resu...

In this study, effect of MAPE (maleic anhydride polyethylene) as the compatibilizer on the mechanical properties of wood-flour polyethylene composites has been investigated by using Dynamic Mechanical Analysis (DMA). Composites were made at 25% and 50% by weight fiber contents and 1% and 2% compatibilizer respectively. Controls were also made at the same fiber contents without the compatibilize...

e consider the effects of adding a PIB-PDMS diblock copolymer as a compatibilizer in model lends composed of polyisobutylene PIB and polydimethylsiloxane PDMS . The ratio of PIB to DMS was varied from 20:80 to 80:20 and, hence, these blends are dubbed “concentrated” blends. ost experiments were conducted on blends containing 0.01 or 0.1 wt. % compatibilizer. All lends had a droplet-matrix morph...

The use of mixtures of synthetic and natural polymers is a potential option to reduce the pollution by plastic waste. In this work, the method for the chemical modification of chitosan with poly(lactic acid) was developed; then, the preparation of films of blends of polyethylene and chitosan-poly(lactic acid) produced by an extrusion method using polyethylene-graft maleic anhydride as a compati...

Waste electrical and electronic equipment (WEEE) is growing rapidly, and the plastics within WEEE have an important role in fulfilling the recovery and recycling targets defined in the European WEEE Directive. This study considers recycling of WEEE plastics by making a blend of the different plastics instead of separating them. The mechanical and thermal properties can be enhanced by adding a c...

eactive compatibilization, in which a compatibilizer is formed by an interfacial coupling between wo reactive polymers, is commonly used when blending immiscible homopolymers. We consider eactive compatibilization using two multifunctional reactive polymers, which leads to a rosslinked copolymer at the interface. Experiments were conducted on model blends of olydimethylsiloxane PDMS and polyiso...

This work presents new results on using organoclay with an appropriate polymeric compatibilizer as rheology-modifying additives for extrusion foaming of a linear polypropylene (PP), which by itself does not display strain hardening in extensional flow of the melt. The uniaxial melt-extensional viscosity behavior of several nanocomposites prepared with varying ratio of bound maleic anhydride to ...

The preparation of composites of synthetic and natural polymers represent an interesting option to combine properties; in this manner, polypropylene and chitosan extruded films using a different proportion of components and polypropylene-graft-maleic anhydride (PPgMA) as compatibilizer were prepared. The effect of the content of the biopolymer in the polypropylene (PP) matrix, the addition of c...