The construction and electrochemical response characteristics of poly(vinyl chloride) matrix ion-selective electrodes (ISEs) for dextromethorphan (DXM) hydrobromide are described. The membranes incorporate ion-association complexes of DXM with reineckate salt {[Cr(NH3)2(SCN)4]NH4} or phosphomolybdic acid [H3(PMo12O40)], as electroactive materials and dioctylphthalate or dibutylsebacate as a pla...

The effect of nanoconfinement on the glass transition temperature T(g) in thin polymer films is studied as a function of added small-molecule diluent or plasticizer. The decrease [increase] in T(g) found in nanoconfined, neat polystyrene [poly(2-vinyl pyridine)] is suppressed by added diluent, with 13-20 nm thick polystyrene films exhibiting bulk T(g) upon addition of 9 wt % pyrene or 4 wt % di...

Studies were made of the penetration of two polydispersed dioctylphthalate aerosols of different particle size distri bution through 9 mil HV-70 type filter paper with and without pinholes at several different air velocities. It was found, as was expected from elementary considera tions, that the penetrations of the two aerosols of different particle size differed greatly for an intact filter, ...

Jiro Kumaki,1 Takeji Hashimoto,1,2 and Steve Granick3 1Hashimoto Polymer Phasing Project, ERATO, JRDC, Keihanna Plaza, Seika, Kyoto 619-02, Japan 2Division of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 606-01, Japan 3Department of Materials Science and Engineering, University of Illinois, Urbana, Illinois 61801 (Received 27 February 1996) Phase separation occurre...

(1) High-efficiency particulate air (HEPA) filtration: the HEPA-filtration system used a prefilter screen, a bag filter (Eurovent [EU] 8 rating), and a HEPA filter (EU13 rating). (2) 2×-low-cost filtration: The low-cost-filtration system contained mosquito netting (prefilter), 2 fiberglass furnace filters, and 2 electrostatic furnace filters. (3) Bag filtration: Bag filtration involved the use ...

Novel ionophores comprising various hydroxide and amine structures were immobilized onto poly(vinyl chloride) (PVC) matrices, and these were examined to determine Ti(III) selectivity. To predict the selectivity of Ti(III), a PVC membrane was used to investigate the binding of Ti(III) to c-methylcalix[4]resorcinarene (CMCR). The study showed that the chelating ligand, CMCR, was coordinated selec...