A luminescence method was developed to screen residues of enrofloxacin (ENRO) and its metabolite, ciprofloxacin (CIPRO), in swine liver. Target analytes were extracted in acetonitrile/1.5% trifluoroacetic acid/NaCl, cleaned up by dispersive liquid-liquid microextraction (DLLME), and finally detected by terbium-sensitized luminescence (TSL) using a time-resolved luminescence photometer. CIPRO yi...

A sensitive method was developed to speciate and quantify As(III) and As(V) in fruit juices. At pH 3.0, As(III) and ammonium pyrrolidine dithiocarbamate (APDC) formed a complex, which was extracted into CCl4 by dispersive liquid-liquid microextraction (DLLME) and subsequently quantified by hydride generation-atomic fluorescence spectrometry (HG-AFS). After As(V) was reduced by thiosulphate at p...

Um método simples de microextração líquido-líquido dispersiva com solidificação da gota orgânica flutuante (DLLME-SFO), prévio à espectrometria de absorção atômica em chama, foi usado com sucesso na separação e pré-concentração de cobre em amostras de cabelo humano e chá. O método proposto é simples, barato e altamente preciso. Neste estudo, a otimização de parâmetros experimentais que influenc...

The antibiotic residues in milk are a well-known serious problem and pose several health hazards to consumers. We have described a simple, rapid, and inexpensive DLLME-HPLC/UV technique for the extraction of chloramphenicol and florfenicol residues in milk samples. Under the optimum conditions, linearity of the method was observed over the range 0.02-0.85 µg/L with correlation coefficients > 0....

Um método de extração de Fe(III) em amostras de água prévio à determinação espectrométrica foi desenvolvido. Microextração dispersiva líquido-líquido (DLLME) foi usada com sucesso como método de preparação de amostras para espectrometria de absorção atômica por chama (FAAS). Na abordagem proposta, 8-hidroxiquinolina (oxina) foi usada como agente quelante, clorofórmio e metanol foram selecionado...

A new method of dispersive liquid-liquid microextraction (DLLME) combined with UV-Vis spectrophotometry was proposed for the determination of trace nickel using 2,2'-Furildioxime as chelating and spectrophotometric reagent. In the proposed approach chloroform and ethanol were used as extraction and dispersive solvents, respectively. Some factors influencing the extraction efficiency of nickel a...

A simple microextraction method based on solidification of a floating organic drop (SFOD) was developed for preconcentration of lead prior to its determination by electrothermal atomic absorption spectrometry (ETAAS). Ammonium pyrolidinedithiocarbamate (APDC) was used as complexing agent, and the formed complex was extracted into a 20 μL of 1-undecanol. The extracted complex was diluted with et...

In this research, a rapid, reliable and selective dispersive liquid-liquid microextraction (DLLME) followed by direct injection of microdroplet to graphite furnace atomic absorption spectrometry (GF-AAS) method for the determination of ultra-trace amounts of Ag(I) was developed. Effect of the important experimental parameters on the extraction efficiency of Ag(I) was investigated using response...