msu-s mesoporous catalyst with [sio2]/[al2o3] ratio of 55 was synthesized using tetrapropylammonium hydroxide (tpaoh) as a structure directing agent and hexadecyltrimethylammonium bromide (ctab) as a surfactant. the catalytic activity of the calcined sample was evaluated for the dehydration of methanol to dimethyl ether (dme) in a vertical fixed bed microreactor at a weight hurly space velocity...

h-zsm-5 nano-zeolites were synthesized by hydrothermal method using tetrapropylammonium hydroxide (tpaoh) as a template in the presence of various tpabr concentrations. the effect of different tpabr/tpaoh molar ratios was studied on the catalytic performance of dehydration of methanol to dimethyl ether (dme) in a fixed bed reactor under the same operating conditions (t=300°c, p=1 atm, and whsv=...

H-ZSM-5 nano-zeolites were synthesized by hydrothermal method using tetrapropylammonium hydroxide (TPAOH) as a template in the presence of various TPABr concentrations. The effect of different TPABr/TPAOH molar ratios was studied on the catalytic performance of dehydration of methanol to dimethyl ether (DME) in a fixed bed reactor under the same operating conditions (T=300°C, P=1 atm, and WHSV=...

Being reactive and spontaneously combustible, dried Victorian brown coals can not be exported, and have to be used in mine-mouth power stations which also suffer from low efficiency and high CO2 emission. Synthesis of dimethyl ether (DME) is an option for the production of liquid fuel, a transportable product for power generation and transportation. This paper presents a steady-state process mo...

The direct synthesis process of dimethyl ether (DME) from syngas in slurry reactors is considered to be promising because of its advantages in caloric transfer. In this paper, the influences of operating conditions (temperature, pressure and weight hourly space velocity) on the conversion of CO, selectivity of DME and methanol were studied in a stirred autoclave over Cu-Zn-Al-Zr slurry catalyst...

PtX technologies are one major building block of the future energy system based on renewables sources. Dimethyl ether (DME) is an important product that can be used as intermediate production CO2-neutral base chemicals. New applications lead to increase global and optimization process efficiency, especially when considering decentralized synthesis. This review article puts some spotlights recen...

In this study performance characteristics of ammonia engines using direct injection strategies are investigated. Ammonia is a carbon-free fuel, and thus its combustion does not produce carbon dioxide, a critical greenhouse gas. Ammonia can be produced by using renewable energy sources (e.g., wind and solar) and used as an energy carrier. Recent research also has shown that the efficiency of sol...

The salt metathesis reaction between one equivalent of SmI2(THF)2 and two equivalents K(C5Me4H) in THF afforded single crystals the unusual, toluene-soluble, asymmetric bimetallic Sm(II)/Sm(II) complex, (C5Me4H)2SmII(μ-η3:η5-C5Me4H)SmII(C5Me4H)(THF)2, instead expected product, (C5Me4H)2SmII(THF)2. toluene-insoluble products this can be worked up 1,2-dimethoxyethane (DME) to provide X-ray qualit...

Based on a global kinetics of direct dimethyl ether (DME) synthesis process from syngas, a steady-state one-dimensional mathematical model for the bubble column slurry reactor (BCSR) has been established. It was built on the assumption of plug flow of gas phase, sedimentation-dispersion model of catalyst grains and isothermal chamber regardless of reaction heats and rates for the design of an i...