In this paper, the effect of cationic and anionic ion sizes on the charge storage capability of graphene nanosheets is investigated. The electrochemical properties of the produced electrode are studied using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques in 3M NaCl, NaOH, and KOH electrolytes. Scanning electron microscopy (SEM) is used to characterize the mi...

In the commentary to our paper [Electrochimica Acta 63 (2012) 55], Roling and Drüschler raised a very important issue regarding the measurements and comparison of the differential and integral capacitances retrieved using electrochemical impedance spectroscopy (EIS). They clearly explained that EIS measures differential capacitance rather than integral capacitance. The present letter aims to co...

In this work, electrochemical methods such as Tafel polarization and electrochemical impedance spectroscopy (EIS) were used to study the inhibition efficiency of Nettle leaves hydroalcoholic extract as a green corrosion inhibitor of API 5L carbon steel in 0.5 M H2SO4 solution. The results showed that the inhibition efficiency was increased with increasing the concentration of the extract and th...

We present an integrated label-free biosensor based on surface plasmon resonance (SPR) and Faradaic electrochemical impedance spectroscopy (f-EIS) sensing modalities, for the simultaneous detection of biological analytes. Analyte detection is based on the angular spectroscopy of surface plasmon resonance and the extraction of charge transfer resistance values from reduction-oxidation reactions ...

The effect of Mentha spicata L. extract on the corrosion behaviour of carbon steel in 1.0 M HCl solution was investigated using polarization, electrochemical impedance spectroscopy (EIS) and electrochemical noise (EN) techniques. The solution containing 250 ppm of the ethanolic solution of extract showed the highest inhibition efficiency (IE). The effect of temperature on the rate of corrosion ...

The validity of estimating the solid phase diffusion coefficient, D s , of a lithium intercalation electrode from impedance measurement by a modified electrochemical impedance spectroscopy ~EIS! method is studied. A macroscopic porous electrode model and concentrated electrolyte theory are used to simulate the synthetic impedance data. The modified EIS method is applied for estimating Ds . The ...

In this work, we fabricated an electrochemical sensor based on trimethyloctadecylammonium bromide and multi-walled carbon nanotubes-Fe3O4 hybrid (TOAB/MWCNTs-Fe3O4) for sensitive detection of tetrabromobisphenol A (TBBPA). The nanocomposite was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and Fourier transform infrared spectroscopy (FT-IR) techniques. The ele...

to improve the corrosion protection of copper metal, 0.01m concentration of 1h-1,2,4-triazole-3-thiol (tat) was incorporated into the hybrid sol-gel monolayers containing 3-glycidoxypropyltrimethoxysilane (gptms) and tetraethoxysilane (teos). it was further subjected to hydrolysis and condensation reaction to form a sol-gel matrix. the tat-doped hybrid sol-gel coating was applied over the coppe...

in this study, we explained a nanobiosensor for dna sequence detection, featuring sequence specificity, cost efficiency, speed, and ease of use. without the need for labels or indicators, it may be ideal for the detection of biological agents. this review describes recent advances in electrochemical impedance spectroscopy (eis) with an emphasis on using nanoparticles and nanotechnology. a power...

In this study, the effects of forming method (extrusion) and environmental factors (solution pH and temperature) on the corrosion performance of AZ91 magnesium alloys were investigated using potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM) and salt spray techniques. The polarization test results of the specimens showed that simple sh...