نتایج جستجو برای: furans

تعداد نتایج: 955  

Journal: :Chemical & pharmaceutical bulletin 2012
Yukiko Akai Yukako Tabuchi Kumiko Ando Azusa Ito Yoko Sakata Ikuo Kawasaki Takahiro Ohishi Masayuki Yamashita Shunsaku Ohta Kiyoharu Nishide Yoshitaka Ohishi

A series of benzo[b]furan derivatives having a five-membered heterocyclic substituent at the 2-position were prepared from 2-(1-chloro-2-formylvinyl)benzo[b]furans (2) and 2-(4-alkylcarbamoylbuta-1,3-dienyl)benzo[b]furans. These 2-heterocyclic benzo[b]furans were evaluated for their cysteinyl leukotriene receptor (cysLT1, cysLT2) inhibitory activity. Several compounds showed moderate inhibition...

Journal: :Chemistry 2015
Larissa Pauli René Tannert Robin Scheil Andreas Pfaltz

Enantioselective hydrogenation of furans and benzofurans remains a challenging task. We report the hydrogenation of 2- and 3-substituted furans by using iridium catalysts that bear bicyclic pyridine-phosphinite ligands. Excellent enantioselectivities and high conversions were obtained for monosubstituted furans with a 3-alkyl or 3-aryl group. Furans substituted at the 2-position and 2,4-disubst...

Journal: :Organic & biomolecular chemistry 2017
Debanjan Bakshi Anand Singh

A new disconnection toward tri- and tetrasubstituted furans has been conceptualized and demonstrated. A mild, base-mediated reaction of an allenoate pronucleophile with α-halo ketones/dicarbonyl compounds results in a Csp2-alkylation/enolization/O-vinylation sequence to ultimately afford substituted furan derivatives. The reaction offers a broad scope, provides a facile access to alkyl and aryl...

Journal: :Angewandte Chemie 2014
Jędrzej Wysocki Nuria Ortega Frank Glorius

An enantioselective hydrogenation of disubstituted furans has been developed by using a chiral ruthenium catalyst with N-heterocyclic carbene ligands. This reaction converts furans into valuable enantioenriched disubstituted tetrahydrofurans.

2016
Sónia P. M. Ventura Paulo de Morais Jaime A. S. Coelho Tânia Sintra João A. P. Coutinho Carlos A. M. Afonso

Furans and their derivatives are well-known chemical building blocks common in plant biomass, and are abundantly used in food, medicines and industrial processes. As a bio-renewable resource, obtainable from the abundant and inexpensive lignocellulosic biomass, there is a growing interest in their study, physico-chemical characterization and application. Due to their biological origin, there is...

2014
Olushola Sunday AYANDA

Polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), dioxins and furans are persistent organic pollutants with well-known toxicity and carcinogenic activity. These organic pollutants have the tendency to bioaccumulate, present little or no biodegradation and subsequently, could cause a menace to the ecosystems and human health. This review discusses the occurrence, fate an...

Journal: :Dalton transactions 2011
Deepak Gupta Palanisamy Rajakannu Bhaskaran Shankar Ramasamy Shanmugam Firasat Hussain Biprajit Sarkar Malaichamy Sathiyendiran

Neutral, stable and luminescent metallacycles decorated with furan units, a 2D rectangle with four furans and a 3D trigonal prism with six furans, were synthesized from readily accessible starting materials through a fac-Re(CO)(3)-directed approach.

2015
Robert W. Foster Laure Benhamou Michael J. Porter Dejan-Krešimir Bučar Helen C. Hailes Christopher J. Tame Tom D. Sheppard

The [4+2] cycloaddition of 3-alkoxyfurans with Nsubstituted maleimides provides the first general route for preparing endo-cantharimides. Unlike the corresponding reaction with 3H furans, the reaction can tolerate a broad range of 2-substitued furans including alkyl, aromatic, and heteroaromatic groups. The cycloaddition products were converted into a range of cantharimide products with promisi...

2017
Hemant Kumar Marco W. Fraaije Manuel Ferrer

Various furans are considered as valuable platform chemicals as they can be derived from plant biomass. Yet, for their exploitation, follow-up chemistry is required. Here we demonstrate that Baeyer-Villiger monooxygenases (BVMOs) can be used as biocatalysts for the selective oxidation of several furans, including 5-(hydroxymethyl) furfural (HMF) and furfural. A total of 15 different BVMOs were ...

Journal: :Journal of the Air & Waste Management Association 2001
K J Fritsky J H Kumm M Wilken

Phoenix Services, Inc., owns and operates the Baltimore Regional Medical Waste Incinerator in Baltimore, MD. New regulations for dioxins and furans imposed a limit that was considerably below historical emission levels. To determine a method to comply with the new dioxin/furan regulations, Phoenix Services performed trials with powdered activated carbon (PAC). Although the results with carbon w...

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