n-(diphenylphosphino)triethyl- and tributylammonium salts are introduced as easily prepared, cheap and stable ionic liquids that act as the condensing agent and media for the efficient esterification of acids with alcohols and phenols. this class of ionic liquids is immiscible with the ester products and thus allows simple and easy separation of the desired products from the reaction mixture.

New sulfonic acid functionalized ionic liquids (SAFILs) with bis(trifluoromethylsulfonyl)imide anions were synthesized. These ionic liquids are strong Brønsted acids and can solubilize metal oxides. Water-immiscible SAFILs were used as organic phases in solvent extraction studies.

Ionic liquids containing the hexafluoroacetylacetonate anion are immiscible with water and they exhibit strong metal-complexing ability.

This paper presents an interface tracking method for modelling the flow of immiscible metallic liquids in mixing processes. The methodology can provide an insight into mixing processes for studying the fundamental morphology development mechanisms for immiscible interfaces. The VOF method employed here utilises the piecewise linear for interface construction scheme as well as the continuum surf...

Abstract A novel method for measuring the interfacial liquid film thickness between immiscible liquids of a slug/droplet in a micropipe is proposed. This method is capable of measuring an oil slug/droplet in water with the relative refractive index (m) between the immiscible liquids very close to one in a capillary tube. Unlike the measurement configuration for an air slug in water, an optical ...

Large macromolecules with hydrophobic backbones are known to assemble at the interface between immiscible liquids. This assembly is often unpredictable because of the subtle interplay among hydrophobic interactions, hydrophilic solvation, structural constraints, and the thermodynamics of adsorption. In these studies, we employ vibrational sum frequency spectroscopy and interfacial tension measu...

Several processes involve two immiscible liquid phases with dispersed drops surrounded by a continuous phase. The drops coalesce for joining their mother phase. This phenomenon occurs in many industrial mixing, separation, as well as in environmental processes. This paper is focused on the problem of the coalescence of a single drop at the planar interface of two immiscible liquids. An original...