Magnesium is an abundant element in the environment. Magnesium ion sensing by fluorescence spectral method is of importance due to the need for the detection of the metal in the human body and the environment. In this paper, we report the Mg2+ ion sensing behavior of the phenylhydrazone derivative of a difluorenylpiperidin-4-one. The preparation method of this compound is simple. The compound s...

Radiation enhanced diffusion at the surface of metals has been observed and studied for low-energy nitrogen ions at the surface of copper. The displacement of the target atoms during irradiation creates vacancies and other defects near the surface, thus enhancing the diffusion of implanted materials toward the surface and also into the solid. The mechanism has been studied here by a specia...

The interaction of hGH with some metal ions ( ) at 27°C in NaC1 solution, 50 mM was studied using Isothermal titration calorimetry. There is a set of three identical and non-interacting binding sites for binding of all these metal ions, expect . The intrinsic association equilibrium constants () are not very different for  and , and also their molar enthalpies of binding (KJ/mol for  and  KJ/mo...

As the electrochemical method, the Fast Fourier Transform (FFT) Stripping Cyclic Voltammetry detection method was designed for measurement and monitoring of adsorbed mercury ions by new modified adsorbent based on mesoporous silica as a new adsorbent. In this respect, SBA-15 as mesoporous silica and 1, 3, 5 Trithiane as effective modifier ligand were chosen, and the modification process was car...

keep in mind the importance of cadmium, cobalt and nickel ions as environmentally and economically strategic heavy metals, the application of two acidic extractants, named bis(2-diethylhexyl)phosphoric acid (dehpa) and 2-thenoyltrifluoroacetone (htta), was assessed for the extraction-recovery of these ions from leached solution of spent rechargeable ni-cd batteries. the conditions for leaching ...

The current study was attributed to uranium (VI) ions adsorption using a anion exchanger resin, Dowex®2x8, in the presence of sulfate anions. Evaluation of operational parameters including contact time, pH, initial concentration of uranium ions, and presence of various anions (including phosphate, sulfate, chloride, fluoride, and nitrate) in the solution was assessed on sorption performance of ...

In this article, theoretical studies on the selective complexation of the halide ions (F¯, Cl¯ and Br¯) and ion pairs (Na+F¯, Na+Cl¯ and Na+Br¯) with the cyclic nano-hexapeptide (CP) composed of L-proline have been performed in the gas phase. In order to calculate the dispersion interaction energies of the CP and ions, DFT-D3 calculations at the M05-2X-D3/6-31G(d) level was employed. Based on t...

In this study, the blast furnace slag was used as absorbing bed and then, its ionic adsorption was studied. For this reason, various experimental parameters such as pH, contact time and the primary ion concentration were investigated. The remaining concentrations of ions such as; Mn2+ and Fe2+ in water were measured by atomic adsorption spectroscopy. The chemical and p...

   In this study, cadmium sulfide nanoparticles (CdS NPs) were prepared, characterized and used as a new adsorbent for simultaneous removal of Pb(II) and Cu(II) ions from aqueous solutions. Using a batch adsorption method, the effects of solution pH, contact time, adsorbent dose, and temperature were studied and optimized. Removal efficiencies, higher than 98% were obtained for both the met...

Magnetic chitosan nanocomposites are one of the more recent advanced groups of adsorbents used to remove contaminants from waste water. In this research, N- Nicotinyl-N', N"-bis (Hexamethylenyl) phosphoric triamide (HE) was used as an additive to form a new nanocomposite with the structure of chitosan / 5% Fe3O4 Nps/10% HE resulting in the highly efficient removal of Cd(II...