Modeling and simulation of Polyhydroxybutyrate (PHB) production by Protomonas extorquens in fed-batch culture were conducted in this research. The fed-batch model, developed for this process, employed a kinetic model proposed by other researchers. Several kinetic models were investigated to choose the best model. The criterion for this selection was goodness of fit (δ2). Haldane kinetic model w...

The kinetic analysis of complex solid-state reactions that involve simultaneous overlapping processes is challenging. A method that involves the deconvolution of the individual processes from the overall differential kinetic curves obtained under linear heating rate conditions, followed by the kinetic analysis of the discrete processes using combined kinetic analysis, is proposed. Different con...

Kinetic modeling is an important issue, whose objective is the accurate determination of the rates of various reactions taking place in a reacting system. This issue is a pivotal element in the process design and development particularly for novel processes which are based on reactions taking place between various types of species. The Fischer Tropsch (FT) reactions have been used as the ki...

Kinetic Monte Carlo simulation was applied to investigation of kinetics and mechanism of oxalic acid degradation by direct and heterogeneous catalytic ozonation. La-containing perovskites including LaFeO3, LaNiO3, LaCoO3 and LaMnO3 was studied as catalyst for oxalic acid ozonation. The reaction kinetic mechanisms of each abovementioned catalytic systems has been achieved. The rate constants val...

in this work the kinetic data demanded for kinetic modeling were obtained in temperatures 350, 400, 450 and 500 oc by conducting experimentations on a fe-cr nanocatalyst prepared from a novel method and a commercial fe-cr-cu one. the collected data were subjected to kinetic modeling by using two models derived from redox and associative mechanisms as well as an empirical one. the coefficients o...

almcm-41 was applied for adsorption of methylene blue (mb) and auramine (au) in single and binary component systems. in the single component systems, almcm-41 represents higher adsorption capacity for mb than au with the maximal adsorption capacity of 2.07×10−4 and 1.15×10−4 mol/g at 25 ˚c for mb and au, respectively. in the binary component system, mb and au exhibit competitive adsorption onto...

the sequencing batch reactors were developed to treat the actual wastewater from ethyleneglycol/ethylene oxide producing industry. four identical reactors with total and effective liquid volumes of 9and 7 l were operated respectively in parallel. laboratory experiments were conducted with different organicloadings of 500, 1000, 1500 and 3000 g-cod/m3.day and the performance of the reactors was ...

in the present study, advanced oxidation treatment, uv/ was applied to decolourisation of acid orange 8 (ao8). the uv radiation was carried out with a 15 w low-pressure mercury lamp. kinetic model for the decolourisation of the dye was developed based on experimental results and known chemical and photochemical reactions. the observed kinetic reaction constant was determined and correlated as a...

biodegradation kinetics of 4-nitrophenol (pnp) in aqueous solution by a gram negative soil bacterium, ralstoniaeutropha was firstly studied in a small scale batch reactor. the degradation of pnp was evaluated at initial pnp concentrations ranging from 3 mg/l to 14 mg/l. the rate of pnp consumption by the bacterium culture was modeled using monod and contois kinetics in batch condition. pnp degr...