This reaserch aims at functionalizing magnetic mesoporous silica with methacrylic acid-3-aminopropyltriethoxysilane (Fe3O4@MCM-41@MAA-APTES) applied for removal of methylene blue from aqueous solution. Several variables (such as pH, dye concentration, adsorbent amount and contact time) have been investigated. Under optimum conditions, maximum capacity of 87.71 mg g-1 of MB was obtained for the ...

A magnetic sorbent with stable and superior magnetic behaviour was developed for His-tagged protein purification by immobilized metal affinity chromatography (IMAC). Magnetic, monodisperse and porous silica microspheres 6 mm in size, with bimodal pore size distribution including both mesoporous and macroporous compartments were synthesized as the base material by a staged-shape template hydroly...

In the present work, well ordered, mesoporous carbon nitride (MCN) sorbent with uniform mesoporous wall, high surface area and pore volume has been fabricated using the simple polymerization reaction between ethylene diamine and carbon tetrachloride in mesoporous silica media, and then modified by TiO2 nanoparticles (Ti-MCN). The structural order and textural properties of the nanoporous materi...

Selective adsorption of free glycerol from crude biodiesel was investigated by using mesoporous silica spheres coated with a thin shell of microporous silicalite-1. A polycrystalline silicalite-1 shell was formed upon first covering the external surfaces of various core templates with discrete silicalite-1 nanocrystals, and this was followed by short hydrothermal treatment to ensure shell unifo...

background: multifunctional core-shell magnetic nanocomposite particles with tunable characteristics have been paid much attention for biomedical applications in recent years. a rational design and suitable preparation method must be employed to be able to exploit attractive properties of magnetic nanocomposite particles.objectives: herein, we report on a simple approach for the synthesis of ma...

Background: Multifunctional core-shell magnetic nanocomposite particles with tunable characteristics have been paid much attention for biomedical applications in recent years. A rational design and suitable preparation method must be employed to be able to exploit attractive properties of magnetic nanocomposite particles. Objectives: Herein, we report on a simple approach for the synthesis of m...

A protonated polyaniline-functionalized SBA-15 mesoporous silica nanomaterial (H(+)-PANI/SBA-15) with high surface area and ideal surface properties for the adsorption of anionic dyes is synthesized. Compared with the conventional emeraldine salt of polyaniline (H(+)-PANI), H(+)-PANI/SBA-15 has a significantly higher adsorption capacity for the anionic dye Orange G and is a more effective sorbe...

recent investigations have been shown that inorganic nanomaterials including gold nanoparticles, nonporous and mesoporous silica nanoparticles, magneticnanoparticles, and quantum dots have shown great potential in bioimaging, targeted drug delivery, and cancer therapies. biocompatibility, ease of synthesis, and ease of surface functionalization are among the significant properties of nonporous ...

We report a preparation method for the synthesis of monodisperse magnetic polymer/silica hybrid microspheres using polymer microspheres incorporated with magnetic nanoparticles as a novel template. Monodisperse, hierarchically mesoporous, silica microspheres embedded with magnetic nanoparticles were successfully fabricated after the calcination of the hybrid microspheres. The magnetic nanoparti...

In this work, Fe3O4@SiO2 nanoparticles were coated with mesoporous silica shell by S-N+I- pathway by using anionic surfactant (S-) and co-structure directing agent (N+). The role of co-structure directing agent (CSDA) is to assist the electrostatic interaction between negatively charged silica layers and the negatively charged surfactant molecules. Prior to the mesoporous shell formation step, ...