The partial oxidation and CO2 reforming of methane were studied on Pt/Al2O3, Pt/ZrO2, and Pt/ Ce–ZrO2 catalysts. The reducibility and the oxygen transfer capacity were evaluated by oxygen storage capacity (OSC). The effect of the support on the cleaning mechanism of the catalyst surface was investigated by the sequence of CH4/O2 and CH4/CO2 pulses. The Pt/Ce–ZrO2 catalyst showed the highest sta...

In this study we developed LaNixAl1-xO3 perovskite systems using a sol-gelmethod (with propionic acid as solvent) to use in methane-reforming reactions for producing synthesis gas. To understand the roles of the nature of the precursor and calcination conditions on the formation of LaNixAl1-xO3, we carried out identifications using NMR, FT-IR, XRD, SEM, and TEM. The precursor struc...

A small-size gasification unit is improved through process optimization to simulate industrial United Gas Improvement Company gasification. It finds that the reaction temperature has important impacts on semicoke catalyzed methane gas mixture. The addition of water vapor can enhance the catalytic activity of reforming, which is due to the fact that addition of water vapor not only removes carbo...

With the actual growth of the natural gas industry in the US as well as the potential and availability of this non-renewable carbon source worldwide, reforming of methane gas is getting increasing attention. Methane can be used for the production of heat or electricity, as well, it can be converted to syngas, a building block that could lead to the production of liquid fuels and chemicals, a ve...

The use of a plasma reformer for the generation of hydrogen rich gas from diesel fuel has been investigated. A system that is normally used for investigating natural gas reforming has been modified in order to investigate the reforming of heavy liquid fuels. The composition of the reformate has been investigated as a function of the composition of the reagents. The use of a one-step reformer/wa...

The intrinsic kinetics and diffusion behaviour of methane steam reforming have been investigated in this work. Measurements of effective diffusivities of the gases present in methane steam reforming have been carried out by using the steady-state technique over wide ranges of temperature and pressure in a modified Wicke-Kallenbach (W-K) type diffusion apparatus. The effects of diffusion limitat...

Exploiting the greenhouse gas CO2 as raw material could be more advantageous than its long-term storage. For instance, CO2 can be used on large scale for the production of COrich syngas with a H2/CO ratio of unity. Such a syngas can be used for the synthesis of commodity chemicals like aldehydes and ketones obtained through carbonylation of alkenes in hydroformulation and can be produced by CO2...

Plasmatron fuel converters have been investigated for the conversion of a wide range of fuels. This paper is a series of papers describing an experimental and computational study of plasmatron methane reformers. This paper presents a model that uses limited mixing and chemical kinetics to investigate the plasma assisted reforming of natural gas. The Partially Stirred Reactor (PaSR) model from t...

We have applied the method to carbon formation in C02 reforming of methane over eight transition metals, starting with a list of 164 elementary steps and published UBI-QEP calculations of their activation energies and using the MECHEM program for combinatorial pathway generation. The predicted coking pattern Fe > Ni > Ru > Rh, Ir, Pd > Cu, Pt is consistent with experimental results from the lit...

Abstract: Hydrogen production via Sorption-Enhanced Chemical-Looping reforming combines hydrocarbons reforming (in this case methane reforming), by chemical-looping auto-thermal reforming, with water-gas shift and carbonation reactions. Both H2 production rate and concentration depend on the chemical equilibrium that is established in the fuel reactor and that is influenced by several parameter...