The EPR spectra of nitroxide spin labels have been simulated as a function of microwave field, H1, taking into account both magnetic field modulation and molecular rotation. It is found that the saturation of the second integral, S, of the first harmonic in-phase absorption spectrum is approximated by that predicted for slow-passage conditions, that is, S approximately H1/1 + PH21, in all cases...

We study the temperature dependence of the orientational mobility of water molecules solvating hydrophobic molecular groups with femtosecond midinfrared spectroscopy. We observe that these dynamics show a strong temperature dependence. At temperatures <30 degrees C the solvating water molecules show a reorientation time >10 ps, which is more than four times slower than in bulk water. With incre...

In order to clarify the molecular mechanism of the reorientation of adsorbed water in wood cell wall during dielectric relaxation process, the temperature and frequency spectrums of the dielectric relaxation process based on adsorbed water in wood, acetylated wood and formaldehyde-treated wood were measured, respectively, within a range of -60-20°C, 30Hz-3MHz and 0-27%m.c. On this basis, the qu...

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