in this paper, plate-like nio nanoparticles were prepared by one-pot solid-state thermal decomposition of nickel (ii) schiff base complex as new precursor. first, the nickel (ii) schiff base precursor was prepared by solid-state grinding using nickel (ii) nitrate hexahydrate, ni(no3)2∙6h2o, and the schiff base ligand n,n′-bis-(salicylidene) benzene-1,4-diamine) for 30 min without using any solv...

In this paper, plate-like NiO nanoparticles were prepared by one-pot solid-state thermal decomposition of nickel (II) Schiff base complex as new precursor. First, the nickel (II) Schiff base precursor was prepared by solid-state grinding using nickel (II) nitrate hexahydrate, Ni(NO3)2∙6H2O, and the Schiff base ligand N,N′-bis-(salicylidene) benzene-1,4-diamine) for 30 min without using any solv...

in this paper, cubic nickel oxide nanoparticles were successfully prepared by solid-state thermal decomposition of nickel(ii) macrocyclic schiff-base complex at 450°c for 3 h without employing toxic solvent or surfactant and complicated equipment. nickel(ii) macrocyclic schiff-base complex was synthesized by the reaction of 1,2-bis(2-formyl-3-methoxyphenyl)propane, nicl2•6h2o and 1,3-phenylened...

Two new nano particles of copper (II) and nickel (II) complexes, [Cu(cd5Clsalen)] (1) and [Ni(cd5Clsalen)] (2) with unsymmetrical tetradentate Schiff base ligand cd5Clsalen={methyl-2-[N-[2-(2-hydroxy-5-choloro-2phenyl) methylidynetrilo]ethyl}amino-1-cyclopentenedithiocarboxylate, were synthesized by hydrothermal method. These compounds were characterized by a variety of physic-chemical techniqu...

In this paper, cubic nickel oxide nanoparticles were successfully prepared by solid-state thermal decomposition of nickel(II) macrocyclic Schiff-base complex at 450°C for 3 h without employing toxic solvent or surfactant and complicated equipment. nickel(II) macrocyclic Schiff-base complex was synthesized by the reaction of 1,2-bis(2-formyl-3-methoxyphenyl)propane, NiCl2•6H2O and 1,3-phenylened...

In this paper, cubic nickel oxide nanoparticles were successfully prepared by solid-state thermal decomposition of nickel(II) macrocyclic Schiff-base complex at 450°C for 3 h without employing toxic solvent or surfactant and complicated equipment. nickel(II) macrocyclic Schiff-base complex was synthesized by the reaction of 1,2-bis(2-formyl-3-methoxyphenyl)propane, NiCl2•6H2O and 1,3-phenylened...

Nickel (II) and copper (II) complexes of highly unsymmetrical tetradentate Schiff base have been synthesized by the template reaction of half-units N-(1-hydroxy-2-acetonaphtone)-1-amino-2-phenyleneimine (HL) and N-(2-hydroxyacetophenone)-1-amino-2-phenyleneimine (HL1) with the glyoxalphenylhydrazone. The complexes have been characterized by elemental analyses, conductance, IR, 1H NMR and UV spe...

nickel (ii) and copper (ii) complexes of highly unsymmetrical tetradentate schiff base have been synthesized by the template reaction of half-units n-(1-hydroxy-2-acetonaphtone)-1-amino-2-phenyleneimine (hl) and n-(2-hydroxyacetophenone)-1-amino-2-phenyleneimine (hl1) with the glyoxalphenylhydrazone. the complexes have been characterized by elemental analyses, conductance, ir, 1h nmr and uv spe...

A new tetradentate N2O2 Schiff base ligand (MeO-bph)2bn = N,N¢-bis(2-hydroxy-4-methoxybenzophenone)-1,4-butanediamine was prepared from the condensation of butane-1,4-diamine with 4-methoxy-2-hydroxybenzophenone and characterized by 1H-NMR spectroscopy and single-crystal X-ray diffraction. Its nickel(II) and copper(II) complexes characterized usin...

In the present work, we report preparation of NiO nanoparticles with well-defined plate morphology by solid-state reaction of NiCl2∙6H2O and the Schiff base ligand N,N′-bis-(3-methoxysalicylidene)benzene-1,4-diamine), as a novel precursor via solid state thermal decomposition method. This method is a simple and environmentally friendly for preparing t...