This paper evaluated a practical approach to the fabrication of arrays of non-spherical nanoparticles by colloidal etching without a mask involving exposure to a low energy ion beam. A spherical nanoparticle array was transferred using a soft nanolithography technique, which is a simple and effective pattern transfer method for nanostructures on the surface of thin adhesive polymers on a planar...

We reported two forms (sphere and wire) of newly fabricated chlorhexidine (CHX)-loaded mesoporous silica nanoparticles (MSNs), and investigated their releasing capacities and anti-biofilm efficiencies. The interactions of the blank MSNs with planktonic oral microorganisms were assessed by field emission scanning electron microscopy. The anti-biofilm effects of the two forms of nanoparticle-enca...

The conformation of cross-linked, monomolecular, polystyrene nanoparticles on a solid substrate is considered as a function of cross-linking degree and substrate surface free energy. It is found that an extreme amount of cross-linking is necessary for the ca. 5-10 nm diameter nanoparticles to retain their original spherical shape, regardless of surface free energy. A lesser amount of cross-link...

piezoelectric microcantilevers (mcs) are a new generation of microbeams used in atomic force microscopes (afms). due to their miniaturization of afms as well as their increased imaging precision and speed, these mcs are more popular than their classical counterparts. given the widespread application of these beams in nanoparticle topography, analysis of their vibrating motion has attracted much...

Molecular dynamics simulations were performed to study the ion and water distribution around a spherical charged nanoparticle. A soft nanoparticle model was designed using a set of hydrophobic interaction sites distributed in six concentric spherical layers. In order to simulate the effect of charged functionalyzed groups on the nanoparticle surface, a set of charged sites were distributed in t...

Sedimentation analysis of nanoparticle (ZrO(2) and SiO(2)) suspensions of different particle sizes in various solvents as nanoparticle model systems was carried out using interference optics in the analytical ultracentrifuge. The particles differed in their morphology: SiO(2) particles were spherical, whereas ZrO(2) particles were in one case spherical and in the second case non-spherical and s...

One of the major challenges in nanomedicine is to improve nanoparticle cell selectivity and adhesion efficiency through designing functionalized nanoparticles of controlled sizes, shapes, and material compositions. Recent data on cylindrically shaped filomicelles are beginning to show that non-spherical particles remarkably improved the biological properties over spherical counterpart. Despite ...

The diffusion process of a single spherical nanoparticle immersed in a fluid solvent is studied by molecular dynamics simulations. When the nanoparticle mass stays constant, it is shown that, at short times, the decay of the nanoparticle velocity autocorrelation function is strongly modified when the particle diameter increases. It is also shown that, at large times, the characteristic algebrai...

The Coulombic interaction in the oriented attachment growth of one-dimensional nanotubes is evaluated via a newly-derived analytical expression of the Coulombic interactions between a spherical attaching nanoparticle and a growing nanotube. The correlation between the interaction and the important growth parameters, including nanoparticle/nanotube size, aspect ratio, and nanoparticle-nanotube s...