Tin is a naturally occurring element. It is a silver-white, malleable, and somewhat ductile metal. The earth's crust contains about 2–3 ppm tin, comprising 0.0006% of the earth's crust. Major uses of tin include cans and containers, electrical, construction, and transportation. Industrially important tin compounds can be categorized as inorganic (those without a tin-carbon bond) and organic (th...

Tin and organotin compounds have been identified in at least 214 and 8 sites, respectively, of the 1,662 hazardous waste sites that have been proposed for inclusion on the EPA National Priorities List (NPL) (HazDat 2004). However, the number of sites evaluated for tin and organotin compounds is not known. The frequency of these sites can be seen in Figures 6-1 and 6-2, respectively. All sites w...

Optically active stannolanes and trigonal bipyramidal pentacoordinated tin complexes were readily prepared by radical cyclization of N-propargylated chiral aza-Morita-Baylis-Hillman adducts induced by Bu(3)SnH. A translocated radical through the cyclization attacked the Bu(3)Sn group in an S(H)2 manner.

Work reported in recent years from this laboratory has outlined the general features of poisoning in animals given diand trialkyl tin salts (Stoner, Barnes, and Duff, 1955). More detailed accounts of the cerebral oedema produced by triethyl tin in rats (Magee, Stoner, and Barnes, 1957) and the bile duct and liver lesions produced by dibutyl tin salts in rats and mice have also been prepared (Ma...

Alkyl compounds of tin chlorides are widely used for the production of plastics in the chemical industry. They inhibit the dissociation of hydrochloric acid from polyvinyl chloride (PVC) and in combination with PVC they are not toxic. However, as free molecules, organic tin compounds are highly toxic in contrast to inorganic tin compounds. The toxic components are dimethyltin chloride and trime...

M icbial Trsform aion of O rgnotin C om punds uder im uated Ldfill C onitions Liöping 2007 The cycling of tin is a topic of concern because of its anthropogenic entry of organotin compounds into the environment. Special attention is given to the transformation of organotins and the methylation of inorganic tin, since these processes often give rise to more toxic formulations. By far the largest...

Five novel tin Schiff base complexes with histidine analogues (derived from the condensation reaction between L-histidine and 3,5-di-tert-butyl-2-hydroxybenzaldehyde) have been synthesized and characterized. Characterization has been completed by IR and high-resolution mass spectroscopy, 1D and 2D solution NMR ((1)H, (13)C  and (119)Sn), as well as solid state (119)Sn NMR. The spectroscopic evi...

The toxicity of selected tin compounds is reviewed. Over the years, a variety of uses has been found for organic and inorganic tin compounds, as fungicides, as stablizers in plastics, moluscicides, and miticides; they have also been suggested as insect chemosterilants and for other industrial uses. Many of these products are unpalatable when mixed into diets and have been suggested as rodent re...

Organotin compounds are used as fungicides and antifouling agents, which are incorporated into paints for use in sea vessels. These compounds have been found to be a threat to the environment. Method development for the determination of total tin in marine sediments by Zeeman GFAAS was studied. The optimum pyrolysis and atomization temperatures for tin analysis were 1100oC and 2300oC, respectiv...