We review and present a few new results of the program of emergent matter as braid excitations of quantum geometry that is represented by braided ribbon networks. These networks are a generalisation of the spin networks proposed by Penrose and those in models of background independent quantum gravity theories, such as Loop Quantum Gravity and Spin Foam models. This program has been developed in...

X-ray absorption and magnetization experiments are used to describe the oxidation states of the rare earth ions R=Ce, PI and Tb in the double layer high-Tc superconducting series RBa2Cu307 and Pb2Sr2R1-,CaXCu3O8. We obtained the same oxidation states for the rare earths in these two classes of compounds, namely, R=Ce tetravalent and R=Pr and Tb trivalent.

Fluorite-structured oxides find widespread use for applications spanning nuclear energy and waste containment, energy conversion, and sensing. In such applications the host tetravalent cation is often partially substituted by trivalent cations, with an associated formation of charge-compensating oxygen vacancies. The stability and properties of such materials are known to be influenced strongly...

In this study, the effect of variety of Nano- additives doping on the hydration resistance of the MgO-CaO system was investigated. Samples were prepared from calcined dolomite and magnesite. Nano-additives that contained cations with various valences (trivalent and tetravalent) used as  a dopant. The bulk density, apparent porosity and hydration resitance were studied and evaluated. Also, phase...

Four serotypes of monovalent live attenuated dengue virus vaccine candidates were tested for reactogenicity and immunogenicity in 49 flavivirus non-immune adult human volunteers. The four monovalent candidates were then combined into a tetravalent formulation and given to another 10 volunteers. Neutralizing antibody seroconversion rates after a single-dose monovalent vaccination ranged from 53%...

Diaryl substituted phosphorus (III) compounds are commonly used motifs in synthesis. Although the basic synthetic routes to these molecules starting from PCl3 well reported, sterically hindered aryl substituents can be difficult introduce, especially if P atom is ortho position another group. This work explores chemistry of bis(biphenyl)phosphorus(III) fragment. As third substituents, H, M, Cl,...

A tetravalent cerium macrocyclic complex (CeLK4) was prepared with an octadentate terephthalamide ligand comprised of hard catecholate donors and characterized in the solution state by spectrophotometric titrations and electrochemistry and in the crystal by X-ray diffraction. The solution-state studies showed that L exhibits a remarkably high affinity toward Ce4+, with log β110 = 61(2) and ΔG =...

Covalent grafting of chromotropic acid (CA) moiety to a glassy carbon electrode was performed by electrochemical reduction of the corresponding diazonium cation generated in situ. Grafted electrodes were subjected to the electrochemical detection of multivalent cations using Fe(CN)(6)(3-/4-) as an electrochemical probe molecule. In the absence of metal cations, redox reaction of the anionic p...

Alkali-doped fullerides show a wide range of electronic phases in function of alkali atoms and the degree of doping. Although the presence of strong electron correlations is well established, recent investigations also give evidence for dynamical Jahn-Teller instability in the insulating and the metallic trivalent fullerides. In this work, to reveal the interplay of these interactions in fuller...