A scale-up study has been performed with three different size reactors to establish the optimum operating conditions for the hydrogen production from synthesis gas by biological water-gas shift reaction using the photosynthetic bacterium Rhodosprilliunt rubrum. Optimum medium composition and operating conditions previously determined in a bench scale 1.25 L continuous stirred tank reactor (CSTR...

effect of water gas shift reaction (co+h2o=co2+h2) on wustite reduction has been investigated by a transient, non-isothermal mathematical model based on grain model. in this model, wustite porous pellet is reduced using syngas, namely a mixture of hydrogen, carbon monoxide, carbon dioxide and water vapor. for this purpose, governing equations containing continuity equation of species and energy...

in this work the kinetic data demanded for kinetic modeling were obtained in temperatures 350, 400, 450 and 500 oc by conducting experimentations on a fe-cr nanocatalyst prepared from a novel method and a commercial fe-cr-cu one. the collected data were subjected to kinetic modeling by using two models derived from redox and associative mechanisms as well as an empirical one. the coefficients o...

Effect of water gas shift reaction (CO+H2O=CO2+H2) on wustite reduction has been investigated by a transient, non-isothermal mathematical model based on grain model. In this model, wustite porous pellet is reduced using Syngas, namely a mixture of hydrogen, carbon monoxide, carbon dioxide and water vapor. For this purpose, governing equations containing continuity equation of species and energy...