Here we report that mesoporous ternary oxide Zn2SnO4 can significantly promotes the crystallization of hybrid perovskite layers and serves as an efficient electron transporting material in perovskite solar cells. Such devices exhibit an energy conversion efficiency of 13.34%, which is even higher than that achieved with the commonly used TiO2 in the similar experimental conditions (9.1%). Simpl...

In view of the increased prospects of Zn2SnO4 as an alternative photoanode for dye sensitized solar cells (DSSCs), we synthesized phase pure Zn2SnO4 nanostructures by a cost effective sonochemical technique. In order to establish the stability of this alternative photoanode in DSSCs, we further explored the interaction of the synthesized Zn2SnO4 with commonly used photosensitizers in DSSCs, suc...

We report synthesis of cetyltrimethyl ammonium bromide (CTAB) stabilized Zn1+xSnO3+x (0 ≤ x ≤1) nano-crystallites by facile cost-effective wet chemistry route. The X-ray diffraction patterns of as-synthesized powders at the Zn/Sn ratio of 1 exhibited formation of ZnSn(OH)6. Increasing the Zn/Sn ratio further resulted in the precipitation of an additional phase corresponding to Zn(OH)2. The deco...

ZnO nanocone arrays on self-assembled Zn2SnO4 base were successfully synthesized via a thermal evaporation method of two-step temperature-rising. The as-prepared ZnO nanocone products had a well crystalline wurzite structure with symmetry about the growth direction along [0001]. Based on the calculation of the lattice misfit between different families of crystal planes of ZnO and Zn2SnO4, Stran...

The interface effect is one of the most important factors that strongly affect the structural transformations and the properties of nano-/submicro-crystals under pressure. However, characterization of the granular boundary changes in materials is always challenging. Here, using tetrakaidecahedral Zn2SnO4 microcrystals as an example, we employed alternating current impedance, X-ray diffraction m...

Development of ternary metal oxide (TMO) based electron transporting layer (ETL) for perovskite solar cell open a new approaches toward efficient a unique strategy for solid state dye-sensitized solar cells (ssDSSCs). In the present investigation, highly porous zinc tin oxide (Zn2SnO4) scaffold nanofibers has been synthesized by electrospinning technique and successfully used for methyl ammoniu...

ZnO nano/microstructures have been formed by thermal evaporation method using ZnO powders mixed with carbon group elements (C, Si, Ge, Sn, or Pb) as the reducing agent. For cases of mixed precursors of ZnO/C, ZnO/Si, and ZnO/Ge, the pure ZnO nano/microstructures are realized, while for ZnO/Sn (ZnO/Pb) systems, the phase of Pb2O3(Zn2SnO4) generally are represented in the ZnO products. The appear...

This work investigates the influence of reaction time (ranging from 12 to 96 h) on the characteristics of zinc stannate (Zn2SnO4) nanoparticles obtained by the hydrothermal method at 200°C. The nanoparticles were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), surface area measurements (BET) and infrared spectroscopy (IR). The results showed that the reaction time ...

This work presents a method for synthesis of high-yield, uniform and band gap tunable Zn2SnO4 nanocubes. These nanocubes can be further self-assembled into a series of novel nanofilms with tunable optical band gaps from 3.54 to 3.18 eV by simply increasing the heat treatment temperature. The Zn2SnO4 nanocube-nanofilm based device has been successfully fabricated and presents obviously higher ph...

In this research, Zn2SnO4 nanorods were prepared and structural properties of the nanorods were characterized, developing of wide-range of the optical behavior of Zn2SnO4 nanorods and the antibacterial activity was also investigated using a microwave-assisted method. A zinc stannate (Zn2SnO4) nanorod was synthesized via facile microwave-assisted method using ammonia with cubic spinel structure....