Two types of one-handed exact helical polymers, coil- and screw-shaped polymers, were synthesized by the two-point-covalent-linking protocol using C2-chiral spirobifluorene (SBF) and C2- or C(s)-symmetric anthraquinone spacers. Central to this protocol is a new aromatic ring-forming reaction based on the stepwise reductive cyclization of bis(aryloxy group)-substituted anthraquinone derivatives....

A recently proposed set of sum rules, based on the pion-Kaon scattering amplitudes and their crossing-symmetric conjugates are analysed in detail. A key role is played by the l = 0 ππ → KK amplitude which requires an extrapolation to be performed. It is shown how this is tightly constrained from analyticity, chiral counting and the available experimental data, and its stability is tested. A re-...

Magnetic domain-walls (DWs) with a preferred chirality exhibit very efficient current-driven motion. Since structural inversion asymmetry (SIA) is required for their stability, the observation of chiral domain walls in highly symmetric Pt/Co/Pt is intriguing. Here, we tune the layer asymmetry in this system and observe, by current-assisted DW depinning experiments, a small chiral field which se...

The first series of monodisperse chiral oligofluorenes was synthesized and characterized. Chain length was found to play an important role in solid morphology. Whereas dimer through tetramer are amorphous, pentamer through hexadecamer all show cholesteric mesomorphism with varying degrees of morphological stability against crystallization. Pristine spin-cast films, approximately 90 nm in thickn...

   In chiral and non-chiral electrophoretic resolution of basic drugs, adsorption of analytes to negatively charged capillary wall could lead to poor repeatability of migration time and peak area. In addition, chiral resolutions of basic drugs are commonly performed in low pH buffers. Therefore, longer analysis time due to suppression of electroosmotic flow (EOF) is another dilemma. In this wor...

We study the effect of thermal fluctuations on the topological stability of chiral p-wave superconductors. We consider two models of superconductors: spinless and spinful with a focus on topological properties and Majorana zero-energy modes. We show that proliferation of vortex-antivortex pairs above the Kosterlitz-Thouless temperature TKT drives the transition from a thermal Quantum Hall insul...

We revisit the QCD sum-rule treatment of the isospin-breaking correlator 〈0|T [Aμ(x)Aν(0)]|0〉, in light of the recent claim that a previous treatment produced results incompatible with known chiral constraints. The source of the error in the previous analysis is identified, and a corrected version of the sum-rule treatment obtained. It is then shown that, using input from chiral perturbation th...

A promising approach to the fabrication of materials with nanoscale features is the transfer of liquid-crystalline structure to polymers. However, this has not been achieved in systems with full three-dimensional periodicity. Here we demonstrate the fabrication of self-assembled three-dimensional nanostructures by polymer templating blue phase I, a chiral liquid crystal with cubic symmetry. Blu...

Molecular recognition of representative amino acids (A) by a chiral amido[4]resorcinarene receptor (1(L)) was investigated in the gas phase by ESI-FT-ICR mass spectrometry. The ligand displacement reaction between noncovalent diastereomeric [1(L).H.A](+) complexes and the 2-aminobutane enantiomers (B) exhibits a distinct enantioselectivity with regard to both the leaving amino acid A and the am...