Constitutive modeling of clay is an important research in geotechnical engineering. It is difficult to use precise mathematical expressions to approximate stress-strain relationship of clay. Artificial neural network (ANN) and support vector machine (SVM) have been successfully used in constitutive modeling of clay. However, generalization ability of ANN has some limitations, and application of...

The undrained shear strength of clay is an important index for the calculation bearing capacity foundation soil, soil pressure pit, and analysis slope stability. Therefore, purpose this paper to conduct a comprehensive study combined use machine learning with theoretical equations estimate it. Under Bayesian framework, CatBoost algorithm (CatBoost–Bayesian) based on optimization was developed o...

The mechanical properties of non-vulcanized natural rubber and dialyzed natural rubber-clay nanocomposites have been studied by uniaxial deformations to evaluate the reinforcement efficiency of the clay. We show that while non-rubber molecules contribute to auto-reinforcement, removal of these molecules improves significantly the performance of clay as reinforcement agent. These mechanical prop...

this study aimed to develop techniques for purification of cyanotoxins dissolved in water -particularly those produced by microcystis aeruginosa species - using natural clay, chemically modifiednatural clay, commercial clay and ion exchange and adsorbent resins. except for natural clay, chemical pretreatment was required to increase the adsorption capacity of the treatment materials. all the cl...

Palladium nanoparticles (PdNPs) were deposited on the surface of the modified clay mineral, kaolinite. To improve compatibility, abundance and control of the size of the nanoparticles, kaolinite was modified by the grafting of an amino alcohol (triethanolamine (TEA)) and an ionic liquid (1-(2-hydroxyethyl)-3-methylimidazolium (ImIL)). Characterization techniques (XRD, TGA, solid state (13)C NMR...

The sorption capacity of montmorillonite clay minerals for small cations, such as Ni , can be greatly enhanced by modifying the clay mineral with Al(III). In this study, the mechanisms of Ni uptake by Al-modified montmorillonite were studied using extended x-ray absorption fine structure (EXAFS) spectroscopy of powders and polarized EXAFS spectroscopy of self-supporting clay films to delineate ...

Selective fatty acid hydrophobization of the inner surface of tubule halloysite clay is demonstrated. Aqueous phosphonic acid was found to bind to alumina sites at the tube lumen and did not bind the tube's outer siloxane surface. The bonding was characterized with solid-state nuclear magnetic resonance ((29)Si, (13)C, (31)P NMR), Fourier transform infrared (FTIR), and X-ray photoelectron spect...