The present work analyzes the cognitive process that led Clausius towards the translation of the Second Law of Thermodynamics into mathematical expressions. We show that Clausius’ original formal expression of the Second Law was achieved by making extensive use of the concept of disgregation, a quantity which has subsequently disappeared from the thermodynamic language. Our analysis demonstrate...

We examine the thermodynamic evolution of various evolving systems, from primitive physical systems to complex living systems, and conclude that they involve similar processes which are phenomenological manifestations of the second law of thermodynamics. We take the reformulated second law of thermodynamics of Hatsopoulos and Keenan and Kestin and extend it to nonequilibrium regions, where none...

In this research, the thermodynamic investigation of the tri-generation system is performed by the first and second law of Thermodynamics. The trigeneration system under study consists of three subsystems including the solar subsystem, Kalina subsystem and lithium bromide-water absorption chiller subsystem. The proposed system generates power, cooling and hot water using solar energy. The syste...

The purpose of this note is to see to what extent ideal gas laws can be obtained from simple Newtonian mechanics, specifically elastic collisions. We present simple one-dimensional situations that seem to validate the laws. The first section describes a numerical simulation that demonstrates the second law of thermodynamics. The second section mathematically demonstrates the adiabatic law of ex...

The search for the statistical mechanical underpinning of thermodynamic irreversibility has so far focussed on spontaneous approach to equilibrium. But this is what Brown and Uffink have dubbed ‘minus first law’ thermodynamics. In contrast, second law tells us that certain interventions equilibrium states render initial state ‘irrecoverable’. article, I discuss unusual nature processes in therm...