Publication 1. A. Manceau et al, “Quantitative Zn speciation in smelter-contaminated soils by EXAFS spectroscopy,” Am. J. Sci. (in press, 2000). Figure 3 (top) Soil samples were taken at several depths from a contaminated site. (bottom) Model compounds derived from polarized-EXAFS data at the ESRF and μ-EXAFS data at the ALS provide a good fit with powder-EXAFS spectra from a soil sample, there...

We previously showed that carcinogenic nickel, arsenic, and chromium(VI) compounds induced anchorage independence (AI) in diploid human fibroblastic cells (HFC) derived from foreskins (K. A. Biedermann and J. R. Landolph, Cancer Res., 47: 3815-3823, 1987). To elucidate the role of the valence state of chromium and solubility of chromium compounds in inducing AI, we studied the ability of solubl...

Severe acute chromium poisoning related to dermal involvement has rarely been reported in the literature. We report a case of acute severe chromium poisoning through skin exposure as a result of a chemical burn of 15% of the body surface area and multiple organ failure after short-term exposure. Medical interventions, including mechanical ventilation, continuous venovenous hemofiltration, and p...

Tanneries generate wastewater in the range of 30 to 35L kg skin/hide processed with high salinity, high oxygen demand, high organic loading and a high salt content one of which is chromium which spoils the agricultural land and pollute the ground water. In the present investigation, the bacterial strains were isolated from the contaminated soil which was collected from in and around the tannery...

Hexavalent chromium is an established carcinogenic agent, which is not directly reactive with DNA. Its genotoxicity involves a reduction step, producing reactive oxygen species and radicals, and also lower valence forms which form stable complexes with intracellular macromolecules. The trivalent form of chromium may directly react with the genetic material and has also been shown to generate ox...

The determination of chromium(VI) at high concentrations can be performed spectrophotometrically with 1,5-diphenylcarbazite. The standard determination methods for chromium(VI) in leather like DIN53314 or IUC 18 have a detection limit of 3mg/kg leather. However the detection limit is not enough for lower concentrations. There is a need for lower detection limits because public awareness of hexa...