The adsorption of submonolayer V on an idealized model hematite (0001) surface and subsequent oxidation under atomic O adsorption are studied by density functional theory. The preferred adsorption sites, adsorption energy and configuration changes due to V and O adsorption are investigated. It is found that in most cases V forms threefold bonds with surface O atoms, inducing a large geometry ch...

Hematite concentration is an important climatic proxy for environmental (climatic) studies of soils and sediments. However, the accurate quantification naturally occurring hematite has always been a difficult question, especially those areas with lower concentrations. Diffuse reflectance spectroscopy (DRS) effective method identification detection limits. In this study, we synthesized set sampl...

Developing cheap electrocatalysts for cathodic oxygen reduction in neutral medium is a key factor for practical applications of microbial fuel cells (MFCs). Natural hematite was investigated as a low-cost cathode to improve the performance of microbial fuel cells (MFCs). With hematite-coated cathode, the cell current density stabilized at 330.66 ± 3.1 mA·m−2 (with a 1000 Ω load) over 10 days un...

Bacterial dissimilatory iron reduction is self-inhibited by the production of ferrous [Fe(II)] iron resulting in diminished iron reduction as Fe(II) accumulates. Experiments were conducted to investigate the mechanisms of Fe(II) inhibition employing the dissimilatory metal-reducing bacterium Shewanella putrefaciens strain CN32 under nongrowth conditions in a system designed to minimize precipit...

The composition, structure, and thickness of n-dodecyl-β-D-maltoside self-assembled layers on hematite have been evaluated using infrared external reflection spectroscopy and spectral simulation techniques. From the qualitative and quantitative analysis of the reflection spectra of the same sample recorded at different specific angles of incidence and two polarizations, the orientation of the s...

The Baiyanghe uranium deposit is a currently important medium-sized deposit in the Xuemisitan area, Xinjiang. The hydrothermal alteration in this deposit is closely related to the uranium mineralization of the deposit. In this study, hyperspectral data are collected from drill cores in the Baiyanghe uranium deposit using a FieldSpec4 visible-shortwave infrared spectrometer to study the hydrothe...

The effect of the shell thickness and density on the magnetic properties of composite colloidal particles consisting of a hematite (alpha-Fe(2)O(3)) core and an yttrium oxide (Y(2)O(3)) layer is described. Pure iron oxide colloidal spheres show two clearly different trends of variation of their magnetic susceptibility, chi(m), with temperature. Below T(M) approximately 220 K, chi(m) shows a sli...

In order to conserve the energy used for remediation of harmful metals from aqueous media, an adsorption process was performed. It is efficient and low-cost method with zero carbon emissions as compared other methods. A hematite-based novel nanomaterial loaded onto biochar utilized toxic cadmium metal ions media. Saccharum munja has been employed feedstock prepare biochar. Three adsorbents i.e....