Methanol carbonylation on Rh and Ir organometallic complexes with iodide co-catalysts is currently used to produce acetic acid. Catalyst cost and recovery, as well as the toxic and corrosive nature of iodide compounds, has led a search for alternate routes, such as zeolite acid catalysts for methanol or dimethyl ether carbonylation and dispersed metal oxide domains for the oxidation of ethane, ...

we explore electro-catalytic properties of a system consisting of platinum and palladium nanoparticles dispersed over a nanotubular self-organized tio2 matrix. these electrodes prepared by electroess and microemulsion of palladium and palladium nanoparticles on to tio2 nanotubes, respectively. titanium oxide nanotubes were fabricated by anodizing titanium foil in ethylene glycol (eg) fluoride-c...

16 Multilayered structures with 14 to 50 nm periods composed of titanium and two different 17 titanium oxides, TiO and TiO2, were accurately produced by DC magnetron sputtering 18 using the reactive gas pulsing process (RGPP). Structure and composition of these 19 periodic TiO2/TiO/Ti stacks were investigated by X-ray diffraction (XRD) and 20 transmission electronic microscope (TEM) techniques....

Mn-Ce/FA (M) and Mn-Ce/FA-TiO2 (M), using fly ash (FA) with and without TiO2 as the carriers, were prepared by an integral molding technique. With the increase of TiO2 content, the rates of NO conversion and denitration of Mn-Ce/FA-TiO2 (M) increased, and the NO2 and N2O formation rates decreased. It is found that TiO2 could effectively inhibit the excessive oxidation of NO and the generation o...

Objective(s):  Titanium oxides are known to be appropriate hemocompatible materials which are suggested as coatings for blood-contacting devices. Little is known about the influence of nanometric crystal structure, layer thickness, and semiconducting characteristics of TiO2 on blood hemostasis.   Materials and Methods: Having used sol-gel dip coating method in this study, TiO2 thin films were d...

Titanium dioxide (TiO2), as an important semiconductor metal oxide, has been widely investigated in the field of photocatalysis. The properties of TiO2, including its light absorption, charge transport and surface adsorption, are closely related to its defect disorder, which in turn plays a significant role in the photocatalytic performance of TiO2. Among all the defects identified in TiO2, oxy...