MnCo2O4 (MnO-Co2O3) nanocomposite as a binary oxide has been successfully prepared by precipitation method using cobalt nitrate and manganese nitrate as the precursors and then characterized by scanning electron microscopy-energy dispersive micro-analysis (SEM-EDX) and X-ray diffraction (XRD) techniques. In this work, we report the hydrolysis kinetics reactions of semi mustard (chloroethyl ethy...

Background & Aim: The genus Tanacetum L. belongs to the family Asteraceae and tribe Anthemideae. According to the recent findings the number of Tanacetum species in Iran is 36, of which 12 are endemic. In this study the essential oil composition of Tanacetum chiliophyllum var. oligocephalum was investigated for the first time.   Experimental: The plant was c...

MnCo2O4 (MnO-Co2O3) nanocomposite as a binary oxide has been successfully prepared by precipitation method using cobalt nitrate and manganese nitrate as the precursors and then characterized by scanning electron microscopy-energy dispersive micro-analysis (SEM-EDX) and X-ray diffraction (XRD) techniques. In this work, we report the hydrolysis kinetics reactions of semi mustard (chloroethyl ethy...

A methanol extract of lyophilized Brickellia cavanillesii was quantitatively analyzed using gas chromatographic (GC) techniques. The chromatographic methods employed were (i) GC-flame ionization detector (GC-FID), (ii) GC-mass spectrometry (GC-MS), and (iii) purge and trap GC-MS (P&T GC-MS). Thirteen compounds were identified with a quality match of 90% and above using GC-MS. The compounds were...

3,3'-dichlorobenzidine (DCB) is suspected to be arcinogenic in experimental animal and human. Several studies have investigated excretion of metabolites in urine, hemoglobin adduction and cancer incidence among workers exposed occupationally to DCB. In these researches, metabolites of DCB had a very important role. The purpose of this study was to develop the urinary monitoring method of its me...

A simple and rapid method for determination of mexiletine in pharmaceutical preparations was developed and validated using gas chromatography with flame ionization detection (GC-FID). GC separation was performed in about 5 min using a HP-5 capilary column (30 m x 0.320 mm, 0.25μm). Nitrogen was used as carrier gas at a flow-rate of 2 mL min. After injection of the sample at inlet temperature 25...

A very simple, rapid and sensitive dispersive liquid-liquid microextraction (DLLME) followed by gas chromatography and flame ionization detection (GC-FID) was developed for the determination of phenol and carvacrol in honey samples. A mixture of 100 µl dichloromethane (extraction solvent) and 0.5 ml acetonitrile (disperser solvent) was rapidly injected into sample solution. Thereby a cloudy sol...

The GC of halides (chloride, bromide and iodide) using phenylboronic acid (PBA), 4-bromophenylboronic acid (BPBA), 3, 5 bis (trifluoromethyl) phenylboronic acid (FPBA) and 2,4- dichlorophenylboronic acid (CPBA) as derivatizing reagents are compared. The reactions are carried out in the presence of mercuric salts. The detection systems used are FID and ECD. The thermal analysis of the compou...