Intracellular Cl(-) concentrations ([Cl(-)](i)) of sensory neurons regulate signal transmission and signal amplification. In dorsal root ganglion (DRG) and olfactory sensory neurons (OSNs), Cl(-) is accumulated by the Na(+)-K(+)-2Cl(-) cotransporter 1 (NKCC1), resulting in a [Cl(-)](i) above electrochemical equilibrium and a depolarizing Cl(-) efflux upon Cl(-) channel opening. Here, we investi...

Photolysis of [Ni(II)(μ-Cl)Cl(IPr)](2) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) activates the Ni-Cl bonds to furnish [Ni(I)(μ-Cl)(IPr)](2). Consistent with this photochemistry, a TD-DFT calculation for square planar Ni(ii) centre reveals that light excitation leads to the population of orbitals with σ*(Ni-Cl) character.

The title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl·H(2)O, consists of 4-methyl-anilinium cations, Cl(-) and [SbCl(5)](2-) anions and water mol-ecules. The five Cl atoms bound to Sb [Sb-Cl = 2.4043 (9)-2.6262 (11) Å] form a square-pyramidal coordination environment. In addition, two [SbCl(5)](2-) anions related by an inversion center are joined by Sb⋯Cl inter-actions [Sb⋯Cl = 3.7273 (14) Å] into an ...

This research describes application of a mesoporous nanostructured material based on basic ionic liquid anchored to silica, i.e. nano-2-(dimethylamino)-N-(silica-n-propyl)-N,N-dimethylethanaminium chloride {nano-[DMSPDE][Cl]}, as a highly effective and heterogeneous nanocatalyst for the production of 2-amino-4H-chromenes. The one-pot multi-component ...

in this study, the effect of cognitive load (cl) training on duration and accuracy of bimanual coordination (bc) task was investigated. for this purpose, athletic male students of shiraz university were randomly divided into 4 groups: g1 with low cl, g2 with intermediate cl, g3 with high cl and g4 control. the subjects practiced for 6 weeks, 3 sessions a week, 6 blocks, 12 trials. the subjects ...

The title compound, [Co(C(10)H(8)N(2))(3)]Cl(3)·4H(2)O, contains discrete [Co(bpy)(3)](3+) cations (bpy is 2,2'-bipyridine), Cl(-) anions and water mol-ecules. The [Co(bpy)(3)](3+) complex cation exhibits C(2) symmetry with the twofold axis through the central Co atom and bis-ecting one bpy ligand and one of the Cl(-) anions. The four solvent water mol-ecules and the remaining two Cl(-) anions ...

The synthesis and characterization of new zirconium permethylpentalene (form)amidinate complexes are described: Pn*Zr{N(Dipp)2CH}Cl (1), Pn* = ?8-C8Me6 Dipp 2,6-iPr-C6H3; [Pn*Zr{N(p-tol)2CH}Cl]2 (2), p-tol 4-Me-C6H4; [Pn*Zr{N(iPr)2CMe}Cl]2 (3); Pn*Zr{N(iPr)2CPh}Cl (4); Pn*Zr{N(4-Me-C6H4)2CH}2 (5); [Pn*Zr{N(iPr)2CCH2}]2 (6); Pn*Zr{N(iPr)2CPh}(O-2,6,-Me-C6H3) (7). monohalide derivatives 1–4 demon...