Amine-functionalized mesoporous SBA-15 silica loaded with bovine serum albumin (BSA) has been successfully encapsulated with a thin layer coating of poly(acrylic acid) PAA, with the entrapped BSA being released from the PAA-encapsulated SBA-15 at the higher pH value of 7.4 rather than at the lower pH value of 1.2. This novel drug delivery system has a potential application in the release of pro...

functionalization of multiwalled carbon nanotubes (mwcnts) with nh2 groups under a one pot reaction is studied. during the first step of the reaction, cl and chcl2 groups were attached to the surfaces of mwcnts through an electrophilic addition reaction. in the second step of process, cl atoms were replaced with nh2 and amino groups (ethylene diamine and butyl amine) under a nucleophilic substi...

Gallium phosphide (GaP) surfaces were functionalized with two different molecules that contain an azide moiety at their terminus. Compound 4-azidophenacyl bromide (4AB) is an aryl azide with a bromine group at its opposite terminus that provides easy identification of the molecule's presence on the surface with x-ray photoelectron spectroscopy (XPS). O-(2-aminoethyl)-O'-(2-azidoethyl)pentaethyl...

Gold nanoparticles (Au NPs) have been investigated for a number of biomedical applications, including drug and gene delivery vehicles, thermal ablation therapy, diagnostic sensors, and imaging contrast agents. Surface functionalization with molecular groups exhibiting calcium affinity can enable targeted delivery of Au NPs to calcified tissue, including damaged bone tissue. Therefore, the objec...

We describe a new oblique-incidence reflectivity difference (OI-RD) scanning microscope for high-throughput screening, in microarray format on functionalized glass slides, small-molecule compound libraries for protein ligands. The microscope employs a combination of scan mirror for y-scan and single-axis translation stage for x-scan. For a printed microarray with over 10,000 features, each of 1...

Abstract Taking advantage of the reversible Diels–Alder (DA) reaction, a simple strategy to obtain recyclable epoxy resins is presented. For this purpose, blends furan‐functionalized and nonfunctionalized resin are prepared. After addition diamine bismaleimide, heated at 150 °C for 5 min, where permanent amine/epoxy reaction has taken place upon cooling room temperature DA happened, giving rise...

Selective oxidation of ω-tertiary amine self-assembled thiol monolayers to tertiary amine N-oxides is shown to transform the adhesion of model proteins lysozyme and fibrinogen upon them. Efficient preparation of both secondary and tertiary linker amides as judged by X-ray photoelectron spectroscopy (XPS) and water droplet contact angle was achieved with an improved amide bond formation on gold ...

The effects of amine functionalization of carbon nanotubes (CNTs) and CNTs weight percent (wt. %), on the first bending natural frequencies and damping properties of CNT/epoxy composites are investigated in this paper. CNTs and amine functionalized CNTs (AFCNTs), with two different weight percentages, are used to manufacture the beam shaped specimens. Epoxy, CNT/epoxy (0.25 and 0.5 wt. % of CNT...

MIL-101Cr fully or partially (p) postsynthetically modified with nitro (-NO2) or amino (-NH2) groups was shown to be a robust, water stable, selective and enhanced carbon dioxide (CO2) adsorption material with the amine-functionality. The highly microporous amine-modified frameworks (up to 1.6 cm(3) g(-1) total pore volume) exhibit excellent thermal stability (>300 °C) with BET surface areas up...

In this study, Functionalized chitosan with amine groups was synthesized and coated on the surface of carbon black. The hybrid amino functionalized chitosan-carbon support was employed as an efficient, environmentally friendly heterogeneous catalyst for the transesterification reaction of canola oil and methanol. It was observed that this hybrid was more active than parent polymer at the reaction...