Humic substances (HS) from well waters, fertilizers, and synthetic phenolic polymers were characterized by elemental and UV-VIS spectroscopic analyses. Capillary zone electrophoresis (CZE) with UV absorption detection was used to analyze the lignin-derived phenolic distribution in the degradation residues after alkaline CuO oxidation of HS samples. Eleven phenols with p-acetyl, vanillyl and syr...

The chronic exposure of large segments of the population to disinfected drinking water has necessitated an evaluation of the health effects of the by-products of the chlorination process. This paper reviews the available information concerning the reproductive consequences associated with exposure to disinfection by-products. Four groups of compounds are discussed: the trihalomethanes, in parti...

Humic substances are routinely applied to creeping bentgrass putting greens during times of stress to improve turf health. Confounding effects of added nutrients and other ingredients make it difficult to separate the effects caused by the organic material from additional effects of the supplemental ingredients. Claims made in advertising and marketing of the effectiveness of humic substance pr...

[1] Surface-active organics such as humic-like substances (HULIS) are abundant in aerosol particles and can lower the surface tension of cloud droplets forming on secondary organic and biomass burning aerosols. How fast is the diffusion of these species, relative to the time scale of cloud droplet growth? Here we report surface tension measurements of solutions containing HULIS extracted from s...

Ademir dos Santos,* Wander Gustavo Botero, Iramaia Corrêa Bellin, Luciana Camargo de Oliveira, Julio Cesar Rocha, André Gustavo Ribeiro Mendonça and Antonio Francisco Godinho a Instituto de Química, Universidade Estadual de São Paulo, CP 355, 14801-970 Araraquara-SP, Brazil b Centro de Assistência Toxicológica, Instituto de Biociências, Universidade Estadual de São Paulo, CP 520, 18618-000 Botu...

The influence of the interaction between aquatic humic substances and the algal organic matter (AOM) derived from Microcystis aeruginosa on the fouling of a ceramic microfiltration (MF) membrane was studied. AOM alone resulted in a significantly greater flux decline compared with Suwannee River humic acid (HA), and fulvic acid (FA). The mixture of AOM with HA and FA exhibited a similar flux pat...

The presence of humic substances (HS) in landfill leachate is of great interest because of their structural stability and potential toxicity. This study examined the effects of temperature and waste age on the transformation of HS during in situ aeration of bioreactor landfills. By establishing aerobic conditions, dissolved organic carbon (DOC) rapidly accumulated in the bioreactor leachate. Fr...

The sea-surface microlayer (SML) has different physical, chemical and biological properties compared to the subsurface water, with an enrichment of organic matter i.e., dissolved organic matter including UV absorbing humic substances, fatty acids and many others. Here we present experimental evidence that dissolved organic matter, such as humic acids, when exposed to sunlight, can photosensitiz...