The cytochrome bc(1) complex is the central enzyme of respiratory and photosynthetic electron-transfer chains. It couples the redox work of quinol oxidation and cytochrome reduction to the generation of a proton gradient needed for ATP synthesis. When the quinone processing Q(i)- and Q(o)-sites of the complex are inhibited by both antimycin and myxothiazol, the flash-induced kinetics of the b-h...

A pyridyl-functionalized diiron dithiolate complex, [μ-(4-pyCH2-NMI-S2)Fe2(CO)6] (3, py = pyridine (ligand), NMI = naphthalene monoimide) was synthesized and fully characterized. In the presence of zinc tetraphenylporphyrin (ZnTPP), a self-assembled 3·ZnTPP complex was readily formed in CH2Cl2 by the coordination of the pyridyl nitrogen to the porphyrin zinc center. Ultrafast photoinduced elect...

The involvement of cytochrome b561, an integral membrane protein, in electron transfer across chromaffin-vesicle membranes is confirmed by changes in its redox state observed as changes in the absorption spectrum occurring during electron transfer. In ascorbate-loaded chromaffin-vesicle ghosts, cytochrome b561 is nearly completely reduced and exhibits an absorption maximum at 561 nm. When ferri...

The ultrafast ground state recovery (GSR) dynamics of the radical cation of perylene, Pe(*+), generated upon bimolecular photoinduced electron transfer in acetonitrile, has been investigated using pump-pump-probe spectroscopy. With 1,4-dicyanobenzene as electron acceptor, the free ion yield is substantial and the GSR dynamics of Pe(*+) was found to depend on the time delay between the first and...

The dye-sensitized solar cells (DSSC) have been regarded as one of the most promising new generation solar cells. Tremendous research efforts have been invested to improve the efficiency of solar energy conversion which is generally determined by the light harvesting efficiency, electron injection efficiency and undesirable electron lifetime. In this review, various characteristics of dye-...

Natural convection heat transfer has many applications in different fields of industry; such as cooling industries, electronic transformer devices and ventilation equipment; due to simple process, economic advantage, low noise and renewed retrieval. Recently, heat transfer of nanofluids have been considered because of higher thermal conductivity coefficient compared with those of ordinary fluid...

Herein, recent developments in the production and reactivity of distonic radical anions are reviewed. Known and potential reactions utilizing both the radical and anion centers are highlighted. While work has revealed new distonic radical anion species, limited effort has been to apply them to complex molecule synthesis. Through the development of new photoinduced electron transfer reagents, di...

In this paper, plasma main characteristics such as electron mean temperature, electron number density, and oscillation frequency have been measured experimentally using the double Langmuir probe diagnostic system. In our experiment, the plasma was generated by applying the low pressure dc glow discharge in several common gases. The experimental results indicated the highest plasma density and o...