نتایج جستجو برای: activator generated by electron transfer

تعداد نتایج: 7379511  

Journal: :علوم و تکنولوژی پلیمر 0
لیلا احمدیان اعلم وحید حدادی اصل حسین روغنی ممقانی لیلا حاتمی مهدی سلامی کلجاهی

poly(styrene-co-butyl acrylate)/clay nanocomposites were synthesized via in situ atom transfer radical polymerization using activators generated by electron transfer in the presence of a montmorillonite ion-exchanged with mixed surfactants of dodecyl trimethyl ammonium bromide and vinyl trimethyl ammonium chloride. the living nature of polymerization is confrmed by occurrence of narrow molecula...

This investigation indicates the ability to selectively graft glycidyl methacrylate (GMA) only from the external surface of regenerated cellulose (RC) ultrafiltration (UF) membranes using activator generated electron transfer (AGET) atom transfer radical polymerization (ATRP). This controlled polymerization resulted in epoxy functionalized polymer brush ends. Further reaction of the terminal ep...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه صنعتی اصفهان - دانشکده شیمی 1389

in this thesis, a new optically active poly(amide-imide) (pai) was synthesized by the indirect polycondensation reaction of the l-phenylalanine based diacid chloride and 4,4?-diaminodiphenylether in the presence of triethylamine in n-methyl-2-pyrrolidone. the formation of pai was confirmed by ftir, 1h nmr and elemental analysis. in next step, the surface of titanium dioxide (tio2) nanoparticles...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه رازی - دانشکده علوم 1390

in this thesis, a better reaction conditions for the synthesis of spirobarbiturates catalyzed by task-specific ionic liquid (2-hydroxy-n-(2-hydroxyethyl)-n,n-dimethylethanaminium formate), calcium hypochlorite ca(ocl)2 or n-bromosuccinimide (nbs) in the presence of water at room temperature by ultrasonic technique is provided. the design and synthesis of spirocycles is a challenging task becaus...

A heat transfer model was developed for a new non-electric infant’s transport incubator. The source of heat comprises a super saturated solution of Sodium Acetate and a metal disk (activator) in a plastic container. Estimating the number of the chemical bags required for different ambient temperature was the goal. First the quantity of heat generated by the chemical was appointed through experi...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه شیراز - دانشکده علوم 1391

in this research we have studied the effect of some transition-metals (cu, ag and au) substitutions on two-electron reduction potential of flavins by application of dft method. all geometries have been optimized at blyp level of theory and “6-31+g** + lanl2dz” mixed basis set. the frequency job at the same method and basis sets has been performed to obtain gibbs free energy of compounds. it h...

Journal: :Proceedings of the National Academy of Sciences of the United States of America 2012
Sandra E Hennig Jae-Hun Jeoung Sebastian Goetzl Holger Dobbek

Movement, cell division, protein biosynthesis, electron transfer against an electrochemical gradient, and many more processes depend on energy conversions coupled to the hydrolysis of ATP. The reduction of metal sites with low reduction potentials (E(0') < -500 mV) is possible by connecting an energetical uphill electron transfer with the hydrolysis of ATP. The corrinoid-iron/sulfur protein (Co...

Journal: :Chemical Engineering Journal 2021

Electrochemically activating peroxydisulfate (PDS) can eliminate organic pollution using electron as activator without the involvement of byproducts. Notwithstanding, process suffered from long hydraulic retention time, and activation regime remained unclear. Herein, Pd/Al2O3 catalyst particle electrode for initiating PDS oxidation in cathodic cell degrade various pollutants with varying kineti...

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