A method for the speciation of zinc and copper binding with proteins in human serum was explored by chelating resin (Chelex-100) pre-treatment and inductively coupled plasma mass spectrometry (ICP-MS). It was shown by a SEC (size-exclusion chromatography)-ICP-MS system that albumin-zinc and albumin-copper (loosely-bound species) could be selectively removed from serum by adsorption on the Chele...

Background: Anthropogenic activities release high concentrations of heavy metals into the aquatic ecosystems, which can be absorbed by the aquatic organisms. In this study, the accu-mulation of cadmium (Cd) and arsenic (As) was compared in liver, gill and muscle tissues of toothed carp (Aphanius sophiae) in fresh and salt water. Methods: A total of 175 fish samples were collected from the Sh...

PURPOSE Bisphosphonates have been used to treat osteoporosis for more than ten years. However, complications associated with long-term administration of bisphosphonates, such as nonunion after pelvic insufficiency fracture or osteonecrosis of the jaw, have been recently reported in the literature. We investigated the relationships among the mechanical properties of the intact rat femur as well ...

Infant rice cereals were analyzed for total arsenic, inorganic arsenic (i-As) and the organic arsenic species monomethylarsonoic acid (MMA) and dimethylarsinic acid (DMA) using liquid chromatography inductively coupled plasma mass spectrometry (LC-ICP-MS). Total arsenic concentrations in the samples ranged from 110 ng/gup to 420 ng/g. The i-As in the rice cereals accounted for 33% to 77% of the...

the presence of cr(vi) in groundwater resources is governed by ph and eh of water and its compounds are generally soluble and have more toxicicity and mobility in oxidizing environments. in this article, the cr concentration in ophiolite units, in sediments, and in groundwater resources, and also its potential to contaminate the environment have been investigated in southeast of birjand. during...

Xanthates are commonly used collectors in flotation processes but highly toxic to the aquatic environment. However, there few methods for reliable determination of low xanthate concentrations water samples. In this work, a sensitive, selective, and fast method is presented potassium ethyl (KEX). KEX was determined by high-performance liquid chromatography–inductively coupled plasma–mass spectro...

Scorpion venom is a rich source of biomolecules, which can perturb physiological activity of the host on envenomation and may also have a therapeutic potential. Scorpion venoms produced by the columnar cells of venom gland are complex mixture of mucopolysaccharides, neurotoxic peptides and other components. This study was aimed at cataloguing the elemental composition of venoms obtained from me...

this study was undertaken to determine the concentrations of metals in the muscle and exoskeletonof the crayfish orconectes limosus in order to compare them with other species of crayfish and crustaceans.in addition, we analyzed the correlation between the concentrations of the same element in the exoskeleton andthe meat and different elements accumulated in the same tissue. crayfish individual...