An iron(III)-catalyzed method for the rapid and highly regioselective iodination of arenes has been developed. Use of the powerful Lewis acid, iron(III) triflimide, generated in situ from iron(III) chloride and a readily available triflimide-based ionic liquid allowed activation of N-iodosuccinimide (NIS) and efficient iodination under mild conditions of a wide range of substrates including bio...

We have applied (57)Fe nuclear resonance vibrational spectroscopy (NRVS) to identify protein-bound dinitrosyl iron complexes. Intense NRVS peaks due to vibrations of the N-Fe-N unit can be observed between 500 and 700 cm(-1) and are diagnostic indicators of the type of iron dinitrosyl species present. NRVS spectra for four iron dinitrosyl model compounds are presented and used as benchmarks for...

volatile organic compounds (vocs) are in categories of mankind and environmentally harmful materials. some of vocs are also carcinogenic and mutagen. because of expanded application of these compounds as various domestic and industrial usages, prevention of environmental contamination of these compounds is a substantial issue.  in this study, the effect of zero-valent iron nanoparticles applica...

Survival of Shigella within the host is strictly dependent on the ability of the pathogen to acquire essential nutrients, such as iron. As an innate immune defense against invading pathogens, the level of bio-available iron within the human host is maintained at exceeding low levels, by sequestration of the element within heme and other host iron-binding compounds. In response to sequestration ...

The symmetry of thewavefunction describing the Cooper pairs is one of the most fundamental quantities in a superconductor, but for iron-based superconductors it has proved to be problematic to determine, owing to their complex multi-band nature1–3. Here we use a first-principles many-body method, including the two-particle vertex function, to study the spin dynamics and the superconducting pair...

Granular zero-valent iron (ZVI) has been widely used to construct permeable reactive barriers (PRB) for the in situ remediation of groundwater contaminated with halogenated hydrocarbons. In the anaerobic condition of most groundwater flow systems, iron undergoes corrosion by water and results in hydrogen gas generation. Several studies have shown that some of the hydrogen gas generated at the i...

This article reviews the results of irradiation experiments on iron-based superconductors, with particular emphasis on neutron irradiation. These experiments were either done to foster the theoretical understanding of superconductivity in these compounds by investigating the influence of impurity scattering on the fundamental superconducting properties or to investigate vortex physics and to be...