Previous investigations on the dimerization of n-butenes over Ni-containing Al-MCM-41/ZSM-5 mixed-phase catalysts have shown a correlation between conversion and Ni/(Al + Ni) ratio as well metal–support interaction, which is represented by reduction degree. In present work, both approaches are combined to novel model parameter, allows determine proportion active Ni species Al-Ni site pairs thus...

the mesoporous molecular sieve mcm-41 was covalently grafted with 3-chloropropyl trimethoxylsilane and then was reacted with [cr(salpr)(h2o)]cl, (salpr = n,n'-bis(3-salicylidenaminopropyl)amine) to afford mcm-41 containing cr(salpr) moiety, cr(salpr)mcm-41. powder x-ray diffraction and nitrogen adsorption-desorption analyses revealed that not only the textural characteristics of the support wer...

ti-mcm-41 was synthesized at ph 3, 7 and 11. the titanium content was determined by aas and found to be 4%, 3.2% and 4.5%, respectively. in order to increase the titanium content in ti-mcm-41, ti(iv) ions were grafted onto ti-mcm-41 using ticl4 in toluene and ti(obu)4 in ethanol. the incorporation of ti was determined to be 28% and 30%, respectively. the oxidation of olefins such as cyclopenten...

http://dx.doi.org/10.1016/j.jcis.2016.06.052 0021-9797/ 2016 Elsevier Inc. All rights reserved. Recently, Shao et al. published the paper entitled Rebuttal to the criticism on the paper ‘‘Application of Mn/MCM-41 as an adsorbent to remove Methyl Blue from aqueous solution” [1]. Authors mentioned ‘‘In Section 3.9, adsorption kinetics we have cited the incorrect Ref. [2]. We are so sorry for that...

the direct and indirect methods in solvent media and grinding method in a solvent-free media were used to prepare the mcm-41/zno and mcm-48/zno photocatalysts. the x-ray diffraction (xrd) patterns showed that zinc oxide nanoparticles were put into mcm-41 and mcm-48 substrates and there were zno crystallites as secondary phase in the extra framework of mesoporous materials. the decrease of surfa...

The discovery of mesoporous molecular sieves, MCM-41, which possesses a regular hexagonalarray of uniform pore openings, aroused a worldwide resurgence in this field. This is not onlybecause it has brought about a series of novel mesoporous materials with various compositionswhich may find applications in catalysis, adsorption, and guest-host chemistry, but also it hasopened a new avenue for cr...

The mesoporous molecular sieve MCM-41 was covalently grafted with 3-chloropropyl trimethoxylsilane and then was reacted with [Cr(salpr)(H2O)]Cl, (salpr = N,N'-bis(3-salicylidenaminopropyl)amine) to afford MCM-41 containing Cr(salpr) moiety, Cr(salpr)MCM-41. Powder X-ray diffraction and nitrogen adsorption-desorption analyses revealed that not only the textural characteristics of the support wer...

Ti-MCM-41 was synthesized at pH 3, 7 and 11. The titanium content was determined by AAS and found to be 4%, 3.2% and 4.5%, respectively. In order to increase the titanium content in Ti-MCM-41, Ti(IV) ions were grafted onto Ti-MCM-41 using TiCl4 in toluene and Ti(OBu)4 in ethanol. The incorporation of Ti was determined to be 28% and 30%, respectively. The oxidation of olefins such as cyclopenten...