a simple and reproducible method for the rapid extraction and determination of trace amounts of copper(ii) ions using octadecyl-bonded silica membrane disks modified by 1-(2-pyridyl azo)2-naphtol(pan) and atomic absorption spectrometry was presented. the method was based on complex formation on the surface of the envi-18 disk tm disks followed by stripping of the retained species by minimum amo...

Several margarine base stock candidates have previously been prepared for the purpose of finding better, more oxidatively stable food components: high-saturate vegetable oils, randomized vegetable oils, vegetable oil-hard stock blends, and interesterified vegetable oil-hard stock blends. Here are reported the triacylglycerol compositions of these products, determined using reverse-phase high-pe...

a new and simple method followed by atomic absorption spectrometry has been developedfor indirect determination of ascorbic acid (aa). the proposed method was based on the oxidationof aa to dehydroascorbic acid with cu2+cation(200mgl-1)in an ammonium thiocyanatesolution atph2.4. aa reduces cu2+to cu+followed by the precipitation of cu+ with scn-. then, the excess ofcu2+in the solution was measu...

toxic heavy metals, such as lead (pb) and cadmium (cd) are widely used in industry and their accumulation in the living tissues may cause serious health problems and ecological hazards. twenty four moderately halophilic bacteria isolated from saline environments of iran were used to study their ability to bioremediation of lead and cadmium. amongst them, a gram-negative rod shaped bacterium, de...

The present study was carried out between September 2019 and March 2020 in Yıldız River, which is located within the borders of Yıldızeli district Sivas province used for agricultural irrigation purposes, to determine chemical characteristics river water trace elements. Water’s alkalinity, oxygen demand (COD), chloride (Cl-), calcium (Ca2+), total hardness, phosphate (PO4-P), dissolved reactive...

A field flow preconcentration system for copper determination in seawater is described. Seawater samples are collected and preconcentrated in situ by passing them using a peristaltic pump through a minicolumn packed with Amberlite XAD-4 impregnated with the complexing agent 1-(2-pyridylazo)-2-naphthol. Thus, copper is preconcentrated without the interference of the saline matrix. Once in the la...

In this study the distribution and accumulation indices of some heavy metals in sediments and Tilapia zillii fish in freshwater catchment of River Niger by Ajaokuta Steel Company (ASC), North Central Nigeria were investigated. Water, bottom sediments and Tilapia zillii fish samples were collected upstream and downstream of the drainage column by ASC, Ajaokuta. The sample were digested according...

A method for direct determination of lead in wine and rum samples was developed, using a flow injection hydride generation system coupled to an atomic absorption spectrometer with flame-quartz atomizer (FI-HG-AAS). Lead hyride (PbH(4)) was generated using potassium ferricyanide (K(3)Fe(CN)(6)), as oxidant and sodium tetrahydroborate (NaBH(4)) as reductant. Samples were acidified to 0.40% (v/v) ...

In this study, two flames of iso-pentanol were stabilized on a 60-mm flat flame burner at a low pressure of 15 Torr and analyzed by a flame-sampling molecular-beam setup coupled to a mass spectrometer (MBMS). Singlephoton ionization by synchrotron-generated vacuum-UV radiation with high energy resolution (E/∆E ∼0.04 eV) and/or electron ionization was combined with a custom-built reflectron time...