The SiO2 supported cobalt-iron nano catalysts were prepared by the sol-gel method. This research investigated the effects of (Co/Fe) wt.%, different Co/Fe ratio at different temperature and loading of KCl wt.% for Fisher-Tropsch synthesis (FTS). The results were showed that the catalyst containing 50 wt.% (Co/Fe)/SiO2 (Co/Fe ratio is 70/30) which promoted with 0.6 wt.% KCl is an optimal nano ca...

The Chebyshev orthogonal collocation is a powerful and accurate numerical technique, which is also relatively easy to implement using modern mathematical software (e.g., MATHEMATICA and MATLAB). This technique allows the elucidation of engineering problems involving partial differentials equations or boundary value problems. Six chemical engineering problems concerning the transfer of momentum,...

The use of zeolite catalysts for the refining of products from methanol synthesis and Fisher-Tropsch synthesis was reviewed. The focus was on fuels refining processes and differences in the application to indirect liquefaction products was compared to petroleum, which is often a case of managing different molecules. Processes covered were skeletal isomerisation of n-butenes, hydroisomerisation ...

The structural properties and activities of Cu-Co catalysts used in Fischer-Tropsch synthesis are explored according to their method of preparation. Impregnation, co-precipitation, and a novel method of thermal decomposition were applied to an inorganic precursor complex to generate the Cu-promoted alumina- and silica-supported cobalt catalysts. The precursors and the catalysts obtained by ...

Fischer-Tropsch synthesis is a part of Gas-to Liquids (GTL), Biomass-to-Liquids (BTL) and Coal to Liquids (CTL) technologies, which produce alternatives clean fuels from natural gas, biomass and coal. The catalytic performance of cobalt catalysts in Fischer-Tropsch synthesis strongly depends on the size of cobalt particles in nanoscale range (6-30 nm). Cobalt catalysts are usually prepared via ...

Abstract. A local convergence rate is established for an orthogonal collocation method based on Radau quadrature applied to an unconstrained optimal control problem. If the continuous problem has a sufficiently smooth solution and the Hamiltonian satisfies a strong convexity condition, then the discrete problem possesses a local minimizer in a neighborhood of the continuous solution, and as the...

Fast direct methods are presented for the solution of linear systems arising in highorder, tensor-product orthogonal spline collocation applied to separable, second order, linear, elliptic partial di erential equations on rectangles. The methods, which are based on a matrix decomposition approach, involve the solution of a generalized eigenvalue problem corresponding to the orthogonal spline co...

fischer-tropsch catalysts with high activity and selectivity for olefins were produced using mordenite type sio2/al2o3= 12, 20, 28, 62 zeolite supported iron carbonyl compounds and were characterized by x-ray powder diffraction. the adsorptionof volatile fe(co)5 on the support surface was carried out under vacuum at room temperature. reduction les were monitored by vibrating sample magnetometer...