ABSTRACT Advances in Nuclear Magnetic Resonance (NMR) spectroscopy is a cornerstone structure elucidation of polycyclic 'cage' scaffolds. Due to the compactness these compounds, much overlap, as well unique through-space and bond NMR interactions are frequently observed. This review serves guide for future derivatives by providing some typical relevant aspects characteristic trends, substituent...

Cannabis sativa L. is possibly one of the oldest plants cultivated by man, but has remained a source of controversy throughout its history. Whether pariah or panacea, this most versatile botanical has provided a mirror to medicine and has pointed the way in the last two decades toward a host of medical challenges from analgesia to weight loss through the discovery of its myriad biochemical attr...