this work is presented in five parts. in the first part preparation of the starting complex [pt(c^n)cl(dmso)], 1, in which c^n = n(1),c(2?)-chelated, deprotonated 2-phenylpyridine, and dmso = dimethylsulfoxide, and its reaction with 1 equiv of the biphosphine ligands bis(diphenylphosphino)amine, dppa, or bis(diphenylphosphino)methane, dppm, to give the complex [pt(c^n)cl(dppa)], 2, or [pt(c^n)c...

in this project, some new polyaspartimides, (pas)s, have been synthesized form michael addition reaction between new synthetic bismaleimide (bmi) and some aromatic diamines. a characteristic property of this polyaspartimides is a pendent carboxylic group, which introduced to these polymers from new bismaleimide. bismaleimides (bmi) is one of the interesting compounds, which can be self-polymeri...

in recent years many researchers have been focused on interaction of small molecules with dna. dna is generally the primary intracellular of anticancer drugs, so the interaction between small molecules and dna can cause dna damage in cancer cells, blocking the division of cancer cells and resulting in cell death. the flavonoids are a large group of polyphenolic natural products that are widely ...

flow in natural river bends is a complex and turbulent phenomenon which affects the scour and sedimentations and causes an irregular bed topography on the bed. for the reason, the flow hydralics and the parameters which affect the flow to be studied and understand. in this study the effect of bed and wall roughness using the software fluent discussed in a sharp 90-degree flume bend with 40.3cm ...

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در این پایان نامه مباحثی در مورد نیم گروه های معکوس توپولوژیکی اولیه (مطلقا) h-بسته و فشرده (شمارایی) بدست می آوریم و ساختار نیم گروه های معکوس توپولوژی فشرده شمارایی و نیم گروه های معکوس توپولوژی همنهشت-آزاد را توصیف می کنیم و نشان می دهیم که نیم گروه دو دوری نمی تواند در نیم گروه معکوس توپولوژی فشرده شمارایی نشانده شود. we present some discussions about compact (countably) and (absolutely) h...

a novel acrylic acid-functionalized fe3o4 magnetic nanoparticle with a core-shell structure was developed for utilization as a heterogeneous organosuperacid in chemical transformations. the structural, surface, and magnetic characteristics of the nanosized catalyst were investigated by various techniques such as transmission electron microscopy (tem), thermogravimetric analysis (tga), and ft-ir...

تعاریفی که برای نفی در اکثر کتابهای گرامری فارسی و انگلیسی آمده ناکافی است زیرا نفی می تواند به چند طریق مختلف بکار رود: می تواند متضاد جمله مثبت باشد، می تواند عدم کیفیت مثبت را تاکید نماید، و میتواند به عملی اطلاق شود که انجام نشده است . دان ل.ف . نیلسون معتقد است که نفی در معنای وسیع خود "موضوع بزرگ و سخت توصیفی است " . در این رساله مسائل مختلف مربوط به نفی در فارسی و انگلیسی مورد بررسی قرار...