A two-dimensional retention index system for fatty acid methyl esters (2D-FARI) is proposed. The system is based on the application of different temperature and pressure programs on a single capillary column. A calibration sample is analysed and the retention data is calibrated against a set of reference 2D-FARI values. The calibration models are then applied to predict the 2D-FARI values for c...

Gas chromatographic measurements of the relative retention times of alkyl-substituted arenes and phenols on capillary columns at temperatures of 125 ̊C 140 ̊C have shown that logarithms of retention times increase bi-linearly with the number of carbon atoms in the molecule. It was found that in a high density stationary phase, the longer alkyl side chains of compounds in question are subject to c...

A quantitative structure-property relationship (QSPR) study is suggested for the prediction of retention times of volatile organic compounds. Various kinds of molecular descriptors were calculated to represent the molecular structure of compounds. Modeling of retention times of these compounds as a function of the theoretically derived descriptors was established by multiple linear regression (...

Capillary gas chromatography with nitrogen-specific detection allows rapid screening of numerous drugs of toxicological interest. However, for accurate identification of individual peaks, the system must be well calibrated, e.g., through the use of retention indices (RI). To overcome problems associated with the use of RI's based on homologous series determined with nitrogen-specific detectors,...

Gastrointestinal retention time may affect digestive processes in the horse. To evaluate the effect of processing of grains on mean retention time in different segments of the gastrointestinal tract, 4 Norwegian Cold-blooded trotters (cecally cannulated, approximately 500 kg of BW) were used. Barley, maize, and wheat were all ground, pelleted, extruded, and micronized to create a total of 12 pr...

Corresponding Author: Atsuya Hikosaka, MD Department of Urology, Toyota Kosei Hospital, 500-1, Ibobara, Josui-cho, Toyota, Aichi 470-0396, Japan Tel: +81 565 43 5000 Fax: +81 565 43 5100 E-mail: [email protected] INTRODUCTION Spermatocele, a retention cyst of the scrotum which is or has been in communication with the semen-carrying system,(1) is a relatively common clinical entity. It presents...