A new dimeric orthopalladated complex was synthesized via reaction of 2,3-dimethoxy benzaldehyde oxime with palladium chloride and lithium chloride in methanol as solvent and sodium acetate as base at room temperature. The catalytic activity of this dimeric [Pd{C6H2(-CH=NOH)-(OMe)2-2,3}(µ-Cl)]2 complex as an efficient, air, and moisture tolerant catalyst was investigated in Mizoroki–Heck cross ...

the continuum based approaches don’t provide the correct physics in atomic scales. on the other hand, the molecular based approaches are limited by the length and simulated process time. as an attractive alternative, this paper proposes the fixed interfacial multiscale method (fimm) for computationally and mathematically efficient modeling of solid structures. the approach is applicable to mult...

objectives our aim was to study the relation between vac and the parameters of myocardial mechanics using three-dimensional speckle-tracking echocardiography (3dste). patients and methods we studied 68 normal participants (mean age, 35 ± 12.2 y; 36 [53%] males). vac was measured by the ratio of arterial elastance (ea) to ventricular elastance (ees). the peak systolic value of longitudinal strai...

Positive coupling effect in gas condensate reservoirs is assessed through a pure theoretical approach. A combination of linear stability analysis and long bubble approximation is applied to describe gas condensate coupled flow and relative permeability, thereof. The role of capillary number in gas condensate flow is clearly expressed through closed formula for relative permeability. While the m...

  A new bioactive proline-rich cyclohexapeptide - diandrine C (6), previously isolated from whole plant of Drymaria diandra (Caryophyllaceae), was synthesized through coupling reactions of tetrapeptide unit Boc-Gly-l-Pro-l-Tyr-l-Trp-OH with dipeptide unit l-Pro-Gly-OMe using N,N-diisopropylcarbodiimide (DIPC) as the coupling agent, followed by cyclization of l...

By coupling of Fe2O3@SiO2 particles with metal organic Framework (MOF) the magnetic MOF structure was fabricated. Precipitation and hydrothermal methods were applied for synthesis of core and MOF. Silver nanoparticles were deposited on nickel based metal organic framework surface and magnetic Fe2O3@SiO2@MOF@Ag was obtained. Because of strong coupling between silver nanoparticles and metal organ...