A nanocomposite membrane Cu2+ ion-selective electrode has been constructed using a new compound ethyl 1,2,3,4-tetrahydro-4-(4-methoxyphenyl)-6-methyl-2-oxopyrimidine-5-carboxylat (ETMOC) as a neutral ionophore. The electrode works properly. It responds to Cu2+ ion with a sensitivity of 29.5 ± 0.2 mV/decade over the range 1.0 × 10−9 to 5.0 × 10−1M at p...

the thermodynamic functions such as enthalpy (h), gibbs free energy (g) and entropy (s) ofpyrazole was theoretically studied at 5 different temperatures 25, 30, 35, 40 and 45°c by usinggussian o3, software. first, the structural optimization of isolated pyrazole was done in the gas phaseby appling the density functional theory (b3lyp) level with 3-21g, 6-31g and 6-31+g(d) basissets. moreover, v...

the usage of turbochargers in diesel engines has led to the downsizing of the motors as well as usage of the waste gates in turbochargers. any dimensional reduction in turbochargers and appurtenant leads to an enhancement on the performance of internal combustion engines and in environmental problems in terms of aerodynamic, thermodynamic and mechanical specifications for both engines and turbo...

Thermodynamic theory of phase equilibrium is the main base for the development of the methods of fluid mixtures separation. Thermodynamic approach has a lot of advantages in the practical application when conditions of separation processes are close to the equilibrium. For nonequilibrium processes these advantages fail and one should use another methods including empirical relationships and mod...

The concept of disjoining pressure, developed from thermodynamic and hydrodynamic analysis, has been widely used as a means of modeling the liquid-solid molecular force interactions in an ultra-thin liquid film on a solid surface. In particular, this approach has been extensively used in models of thin film transport in passages in micro evaporators and micro heat pipes. In this investigation, ...